Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Joanne R. Rollo"'
Autor:
Gary R. Burns, Joanne R. Rollo
Publikováno v:
Journal of Non-Crystalline Solids. 127:242-246
A differential scanning calorimetry study of the phase changes undergone by α′-P 4 Se 3 has resulted in a proposed third orientationally disordered phase, β′-P 4 Se 3 . Undercooling of this disordered β′-phase produces a molecular glass with
Publikováno v:
Spectrochimica Acta Part A: Molecular Spectroscopy. 47:811-818
The local environments of the cage molecules in the phases of P 4 Se 3 are analysed with 31 P MAS-NMR and Raman spectroscopy. The 31 P MAS-NMR spectra of the orientationally ordered α and α′,-phases have different chemical shifts for the apical P
Autor:
Robin J. H. Clark, Gary R. Burns, Ward T. Robinson, Michael B. Hursthouse, Helen M. Dawes, Joanne R. Rollo
Publikováno v:
Inorganic Chemistry. 29:2889-2894
Autor:
Gary R. Burns, Joanne R. Rollo
Publikováno v:
Journal of Physics and Chemistry of Solids. 48:347-354
The temperature and pressure dependences of the internal and external first-order Raman-active phonons of crystalline α-P 4 S 3 are shown to provide a sensitive probe of the intermolecular bonding. Comparison with a similar study of α-P 4 Se 3 lead
Publikováno v:
Journal of Raman Spectroscopy. 19:345-351
Polarization data for the Raman-active k = 0 phonons of single crystals of α-P4S3 have been measured at 10 K and at high resolution. Of the 24 external and 60 internal phonons expected for the D2h factor group of α-P4S3 we have observed 16 external
Publikováno v:
Inorganica Chimica Acta. 161:35-38
Mixtures of the four cage molecules P 4 S x Se 3− x ( x =0, 1, 2, 3) were prepared from α-P 4 S 3 and α- P 4 Se 3 . The Raman-active bands of the mixed chalcogenide molecules have been identified and used together with the results of a normal coo
Autor:
Gary R. Burns, Joanne R. Rollo
Publikováno v:
Journal of Physics and Chemistry of Solids. 50:753-762
The Raman spectra of crystalline α′-P 4 Se 3 I 2 , β-P 4 Se 3 I 2 , α-P 4 S 3 I 2 , and β-P 4 S 3 I 2 have been measured as a function of temperature in the range 80–370 K at ambient pressure. In general, the internal and external first-order
Autor:
Joanne R. Rollo, Gary R. Burns
Publikováno v:
Journal of Physics and Chemistry of Solids. 50:399-405
The pressure and temperature dependences of the Raman-active phonons of the molecular crystal P4S10 were investigated. The presence of weak intra-intermolecular coupling is indicated by the softening of the 718.7 and 190.7 cm−1 bands with pressure.
Publikováno v:
Inorganic Chemistry. 25:1145-1149
Publikováno v:
Chemischer Informationsdienst. 17