Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Joan Fraga-Dubreuil"'
Autor:
Edward Lester, Morgan L. Thomas, Martyn Poliakoff, Joan Fraga-Dubreuil, Duncan Housley, Paul A. Hamley, Eduardo Pérez, Jun Li
Publikováno v:
RSC Advances. 6:11289-11294
In this paper we report a strong dependence of the observed performance of the catalyst on the geometry and the configuration of laboratory scale reactors in the continuous aerobic oxidation of p-xylene in supercritical water. Small differences, such
Autor:
Joan Fraga-Dubreuil, Ian Pearson, Walt Partenheimer, Eduardo García-Verdugo, Martyn Poliakoff, Duncan Housley, Paul A. Hamley, W. Barry Thomas, Eduardo Pérez
Publikováno v:
Advanced Synthesis & Catalysis. 351:1866-1876
Presented here is an investigation of the activity and recovery of the homogeneous manganese/bromide catalyst during the continuous flow oxidation of o-xylene, as model substrate, with molecular oxygen (O 2 ) in supercritical water (scH 2 O). Two str
Autor:
Ian Pearson, Chong Yan, A. Stuart Coote, Eduardo García-Verdugo, Martyn Poliakoff, Joan Fraga-Dubreuil, Paul A. Hamley
Publikováno v:
Green Chem.. 10:98-103
Caprolactam (CPL) is a widely used chemical intermediate for the production of Nylon-6. However, existing synthetic routes in industry have severe drawbacks. The development on the synthesis of CPL from 6-aminocapronitrile (ACN), using near- and supe
Publikováno v:
Green Chem.. 10:197-201
We report an investigation of the continuous oxidative dehydrogenation of 4-vinylcyclohexene (VCH) in high pressure steam. Oxidative dehydrogenation reactions such as this are often limited by unselective or total oxidation. We find that these side-r
Autor:
Eduardo García-Verdugo, María José Cocero, Chong Yan, Martyn Poliakoff, Juan García-Serna, Jason R. Hyde, Joan Fraga-Dubreuil
Publikováno v:
The Journal of Supercritical Fluids. 41:82-91
A new two-parameter RTD model based on the one-parameter laminar flow model has been proposed. The model, ‘n-laminar model’, is defined in time domain and considers a generalization of the parabolic velocity profile across radial direction; its m
Autor:
Juan García-Serna, Joan Fraga-Dubreuil, Lucinda M. Dudd, Graham Aird, Eduardo García-Verdugo, Martyn Poliakoff, W. Barry Thomas
Publikováno v:
The Journal of Supercritical Fluids. 39:220-227
The oxidation of benzoic acid (BA) to phenol (the Dow Phenol Process) has been studied in high temperature water (HTW) using a continuous flow system over various metal oxide heterogeneous catalysts: NiO, CuO, Carulite ® , MnO 2 and Al 2 O 3 . Excel
Publikováno v:
Tetrahedron. 59:6121-6130
The first report of the use of task-specific ionic liquid as synthetic equivalent of ionic liquid-phase matrice for the preparation of a small library of 4-thiazolidinones is reported in this paper. The starting (ethyleneglycol)ionic liquid-phase is
Publikováno v:
Organic Process Research and Development (6), 374-378. (2002)
Organic Process Research and Development
Organic Process Research and Development, American Chemical Society, 2002, 6, pp.374-378. ⟨10.1021/op020027y⟩
Organic Process Research and Development, 2002, 6, pp.374-378. ⟨10.1021/op020027y⟩
Organic Process Research and Development
Organic Process Research and Development, American Chemical Society, 2002, 6, pp.374-378. ⟨10.1021/op020027y⟩
Organic Process Research and Development, 2002, 6, pp.374-378. ⟨10.1021/op020027y⟩
New, hydrophilic poly(ethyleneglycol)-ionic liquids have beensynthesized and investigated, based on 1,3-disubstituted imidazolium cations and fluorinated anions (BF4 -, PF6 -,(CF3SO2)2N-, or NTf2 -). A series of typical solvent-free reactions have be
Autor:
Khadidja Bourahla, Joan Fraga-Dubreuil, Jack Hamelin, Mustapha Rahmouni, Jean Pierre Bazureau
Publikováno v:
Catalysis Communications. 3:185-190
Esterification reactions of acetic acid, methoxyacetic acid and methylmalonic acid with neo-pentanol, hexanol, heptanol and decanol have been investigated in three ionic liquids with hydrogen sulphate, dihydrogen phosphate as counteranions and also t
Publikováno v:
Tetrahedron Letters. 42:6097-6100
The preparation and applications in the Knoevenagel and 1,3-dipolar cycloaddition reactions of new grafted soluble liquid phases derived from imidazolium ionic liquids are described. Good yields and high regioselectivity are the features observed wit