Zobrazeno 1 - 2
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pro vyhledávání: '"Jinnie Myung"'
Publikováno v:
Organic Letters. 24:4399-4403
We describe a method to generate alkylidene carbenes via tetramethylammonium-fluoride-induced desilylation of silyl vinyl iodides. The reversible carbene generation from an iodovinyl anion enabled us to unearth mechanistic aspects of the trimethylene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9dc79847ee177f22b0776895846ebb10
https://doi.org/10.1021/acs.orglett.2c01622
https://doi.org/10.1021/acs.orglett.2c01622
Publikováno v:
Tetrahedron Letters. 45:2545-2549
The first example of a dynamic kinetic resolution (DKR) using immobilized amine nucleophiles is described. This approach utilizes a nucleophilic amine attached to a solid phase resin via an organic spacer. The optical purities of the N-substituted α
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2afe81737f52398650bfc03b0f9bba93
https://doi.org/10.1016/j.tetlet.2004.02.004
https://doi.org/10.1016/j.tetlet.2004.02.004