Zobrazeno 1 - 4
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pro vyhledávání: '"Jin-Shan Xiong"'
Publikováno v:
Physical Chemistry Chemical Physics. 25:8507-8514
In a solution of sorbitol (SBT) and Ga(OTf)3 compounds, the Ga3+ cation tends to form five six-coordination complexes, i.e., [Ga(η2O,O-OTf)3], [Ga(η3O2–O4-SBT)2]3+, [(η2O,O-OTf)Ga(η4O2–O5-SBT)]2+, [(η1O-OTf)(η2O2,O4-SBT)Ga(η3O3–O5-SBT)]2
Autor:
Zhen-Bing Si, Jin-Shan Xiong, Ting Qi, Hong-Mei Yang, Han-Yun Min, Hua-Qing Yang, Chang-Wei Hu
Publikováno v:
RSC Advances. 11:39888-39895
The rate-determining reaction step is associated with the C–H bond cleavage of –CH2 group of the first HMF molecule oxidized by [V(O)2(DMA)2]+ species, while counteranion Cl− exhibits catalytically promotive effect.
Publikováno v:
SSRN Electronic Journal.