Zobrazeno 1 - 10
of 53
pro vyhledávání: '"Jin, Dong Yang"'
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
Fluorine-containing moieties show significant effects in improving the properties of functional molecules. Here the authors show diazaphospholene-catalyzed hydrodefluorination of trifluoromethylalkenes to chemoselectively construct gem-difluoroalkene
Externí odkaz:
https://doaj.org/article/258e26d5614e4c298754b5c68c98cab6
Publikováno v:
CCS Chemistry. 5:1163-1175
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6563016144ffb5105804dab6b091c59b
https://doi.org/10.31635/ccschem.022.202201990
https://doi.org/10.31635/ccschem.022.202201990
Publikováno v:
iScience, Vol 23, Iss 2, Pp - (2020)
Summary: Functionalization of α-C–H bonds of tertiary amines to build various α-C–X bonds has become a mainstream in synthetic chemistry nowadays. However, due to lack of fundamental knowledge on α-C–H bond strength as an energetic guideline
Externí odkaz:
https://doaj.org/article/923881905ada4cf487ba2438d7b4dbe5
Publikováno v:
The Journal of Organic Chemistry. 87:15539-15546
The Vilsmeier-Haack reaction is a powerful tool to introduce formyl groups into electron-rich arenes, but its wide application is significantly restricted by stoichiometric employment of caustic POCl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f54172a17e979a74dfe55bcbcfa17388
https://doi.org/10.1021/acs.joc.2c02085
https://doi.org/10.1021/acs.joc.2c02085
Publikováno v:
The Journal of Organic Chemistry. 87:294-300
The metal-free catalytic C-F bond activation of polyfluoroarenes was achieved with diazaphospholene as the catalyst and phenylsilane as the terminal reductant. Density functional theory calculations suggested a concerted nucleophilic aromatic substit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::016bedbbbfb09ceb6935e496848001c9
https://doi.org/10.1021/acs.joc.1c02360
https://doi.org/10.1021/acs.joc.1c02360
Publikováno v:
The Journal of organic chemistry.
Hydroxylamines, represented by 1-hydroxy-2,2,6,6-tetramethylpiperidine (TEMPOH), are widely involved as active species in various chemical and electrochemical oxidations. The electrochemical behavior of TEMPOH is crucial to understanding the mechanis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35ef166b8d8c916d853bb260418d4c92
https://pubmed.ncbi.nlm.nih.gov/36573883
https://pubmed.ncbi.nlm.nih.gov/36573883
Publikováno v:
Data Technologies and Applications. 56:205-222
PurposeIn computational chemistry, the chemical bond energy (pKa) is essential, but most pKa-related data are submerged in scientific papers, with only a few data that have been extracted by domain experts manually. The loss of scientific data does n
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::92620b78c9142afa80213490bfa6e99c
https://doi.org/10.1108/dta-11-2020-0284
https://doi.org/10.1108/dta-11-2020-0284
Publikováno v:
European Journal of Inorganic Chemistry. 26
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cb76b23dad97d0d0aa3c61fdc50a181a
https://doi.org/10.1002/ejic.202200556
https://doi.org/10.1002/ejic.202200556
Publikováno v:
Chemical communications (Cambridge, England). 58(90)
The unique heterocyclic skeletons of N-heterocyclic phosphines (NHPs) endow them with excellent hydridic reactivity, which has enabled NHPs to be applied in a great array of catalytic hydrogenations of unsaturated substrates in the past few decades.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::459b7bfdc13291775e8b3b75294a1cdb
https://pubmed.ncbi.nlm.nih.gov/36305268
https://pubmed.ncbi.nlm.nih.gov/36305268
Publikováno v:
SCIENTIA SINICA Chimica. 51:110-122
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::efee5a59606093a2049d97347fccf9b3
https://doi.org/10.1360/ssc-2020-0177
https://doi.org/10.1360/ssc-2020-0177