Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Jiaxiang Chu"'
Publikováno v:
IUCrData, Vol 9, Iss 6, p x240497 (2024)
In the title compound, [Mn(C68H44N12O4)(C5H8N2)]·2C6H5Cl, the central MnII ion is coordinated by four pyrrole N atoms of the porphyrin core in the basal sites and one N atom of the 2,5-dimethylimidazole ligand in the apical site. Two chlorobenzene s
Externí odkaz:
https://doaj.org/article/3e1f1ca00eb94894b5d9712ddb4c1180
Publikováno v:
IUCrData, Vol 9, Iss 6, p x240496 (2024)
The title compound, [Fe(C84H52N12O4)Cl], crystallizes in space group C2/c. The central FeIII cation (site symmetry 2) is coordinated in a fivefold manner, with four pyrrole N atoms of the porphyrin core in the basal sites and one Cl atom (site symmet
Externí odkaz:
https://doaj.org/article/30e8de46cac64bc4bfad434dc7343f3a
Publikováno v:
Journal of the American Chemical Society. 144(34)
Two borane-functionalized bidentate phosphine ligands that vary in tether length have been prepared to examine cooperative metal-substrate interactions. Ni(0) complexes react with aryl azides at low temperatures to form structurally unusual κ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afcaa63343f6612d05fc01013eb12b43
https://pubmed.ncbi.nlm.nih.gov/35973127
https://pubmed.ncbi.nlm.nih.gov/35973127
Publikováno v:
Inorganic Chemistry. 59:10343-10352
We report the synthesis of new Lewis-acidic boranes tethered to redox-active vanadium centers, (Ph2N)3V(μ-N)B(C6F5)2 (1a) and (N(CH2CH2N(C6F5))3)V(μ-N)B(C6F5)2 (1b). Redox control of the VIV/V couple resulted in switchable borane versus "hidden" bo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f19d2949ef300290807ea057d4191383
https://doi.org/10.1021/acs.inorgchem.0c01464
https://doi.org/10.1021/acs.inorgchem.0c01464
Publikováno v:
Chemistry – An Asian Journal. 14:2629-2638
A sterically encumbering multidentate β-diketiminato ligand, tBu L2 (tBu L2=[ArNC(tBu)CHC(tBu)NCH2 CH2 N(Me)CH2 CH2 NMe2 ]- , Ar=2,6-iPr2 C6 H3 ), is reported in this study along with its coordination chemistry to zirconium(IV). Using the lithio sal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b043c56e5c77de193b9f4000db0b6cd7
https://doi.org/10.1002/asia.201900451
https://doi.org/10.1002/asia.201900451
Publikováno v:
Journal of the American Chemical Society. 140:15375-15383
Recent computational studies suggest that the phosphate support in the commercial vanadium phosphate oxide (VPO) catalyst may play a critical role in initiating butane C–H bond activation through a mechanism termed reduction-coupled oxo activation
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c4a1a4cb6b41a919ed66bb2f0bd1e2a4
https://doi.org/10.1021/jacs.8b09063
https://doi.org/10.1021/jacs.8b09063
Publikováno v:
Accounts of Chemical Research. 51:557-566
Research into transition metal complexes bearing multiply bonded main-group ligands has developed into a thriving and fruitful field over the past half century. These complexes, featuring terminal M═E/M≡E (M = transition metal; E = main-group ele
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1a218354b8bf46315088028f8c101492
https://doi.org/10.1021/acs.accounts.7b00605
https://doi.org/10.1021/acs.accounts.7b00605
Publikováno v:
Organometallics. 36:4620-4625
Scandium terminal imido complex [(NNNN)Sc═NDIPP] (2; NNNN = [MeC(N(DIPP))CHC(Me)(NCH2CH2NMeCH2CH2NMe2)]−, DIPP = 2,6-iPr2C6H3) reacts with 9-borabicyclononane (9-BBN) to give scandium borohydride [(NNNN(B)H)Sc(N(H)DIPP)] (3; NNNN(B)H = [MeC(N(DIP
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::14013b3721ddc0018afebe5cf0dc340b
https://doi.org/10.1021/acs.organomet.7b00452
https://doi.org/10.1021/acs.organomet.7b00452
Publikováno v:
Angewandte Chemie International Edition. 54:6008-6011
The first stable copper borohydride complex [(CAAC)CuBH4] [CAAC = cyclic(alkyl)(amino)carbene] bearing a single monodentate ligand was prepared by addition of NaBH4 or BH3NH3 to the corresponding [(CAAC)CuCl] complex. Both complexes are air-stable an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19d038db6bf646fe47bd986551a3f93a
https://doi.org/10.1002/anie.201500224
https://doi.org/10.1002/anie.201500224
Publikováno v:
Angewandte Chemie. 127:6106-6109
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::05a10c5c4d64dcfebf323971536ad188
https://doi.org/10.1002/ange.201500224
https://doi.org/10.1002/ange.201500224