Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Jian-Hong Bian"'
Publikováno v:
RSC Advances. 11:15841-15846
NBe5Hnn−3 (n = 0–5) (0A–5A) species with a novel planar pentacoordinate nitrogen (ppN) were designed by the isoelectronic substitution of the C atom in planar pentacoordinate carbon (ppC) species CBe5Hnn−4 (n = 0–5) with an N atom. The high
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::62ccb98fc862535fed941f6bbaa84357
https://doi.org/10.1039/d1ra02178h
https://doi.org/10.1039/d1ra02178h
Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp)3− (M = Ca, Sr, Ba)
Autor:
Xiao-Ling Guan, Caixia Yuan, Jian-Hong Bian, Lingfei Hu, Bin Huo, Bo Jin, Gang Lu, Rui Sun, Yan-Bo Wu
Publikováno v:
Chemical Communications. 57:5806-5809
We predicted the stable alkaline earth complexes M(Cp)3− (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the bonding behaviour of transition metals by participating in bonding with t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e22f6ebb7f5e90785ca11b9e4d359f1f
https://doi.org/10.1039/d1cc01753e
https://doi.org/10.1039/d1cc01753e
Publikováno v:
Dalton Transactions. 50:2654-2662
We present a detailed DFT mechanistic study on the first Ni-catalyzed direct carbonyl-Heck coupling of aryl triflates and aldehydes to afford ketones. The precatalyst Ni(COD)2 is activated with the phosphine (phos) ligand, followed by coordination of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de144b2c52c97f400b5e247729dfd6a3
https://doi.org/10.1039/d0dt04121a
https://doi.org/10.1039/d0dt04121a
Autor:
Xiao-Ling Guan, Xue-Feng Zhao, Jian-Hong Bian, Bin Huo, Yan-Bo Wu, Rui Sun, Caixia Yuan, Bo Jin
Publikováno v:
Physical Chemistry Chemical Physics. 22:17062-17067
Computational design has played an important role in planar hyper-coordinate carbon (phC) chemistry. However, none of numerous computationally predicted phC species were subsequently successfully synthesized in the condensed phase, perhaps due to the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::47c6b136e020acd6bb7f9d1a00629939
https://doi.org/10.1039/d0cp01106a
https://doi.org/10.1039/d0cp01106a
Autor:
Sudip Pan, Mingfei Zhou, Qian Wang, Jian‐Hong Bian, Guohai Deng, Guanjun Wang, Gernot Frenking, Yan-Bo Wu, Lili Zhao
Publikováno v:
Angewandte Chemie (International Ed. in English)
We report the synthesis and spectroscopic identification of the trisbenzene complexes of strontium and barium M(Bz)3 (M=Sr, Ba) in low‐temperature Ne matrix. Both complexes are characterized by a D 3 symmetric structure involving three equivalent
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0bdc19b35c908c563a71851d80e5af62
https://doi.org/10.1002/anie.201908572
https://doi.org/10.1002/anie.201908572
Autor:
Bin, Huo, Rui, Sun, Bo, Jin, Lingfei, Hu, Jian-Hong, Bian, Xiao-Ling, Guan, Caixia, Yuan, Gang, Lu, Yan-Bo, Wu
Publikováno v:
Chemical communications (Cambridge, England). 57(47)
We predicted the stable alkaline earth complexes M(Cp)3- (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the bonding behaviour of transition metals by participating in bonding with the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::14a37bd943e4ef6cbc6d50a4b7aa5ffa
https://pubmed.ncbi.nlm.nih.gov/33999984
https://pubmed.ncbi.nlm.nih.gov/33999984
Autor:
Jian-Hong, Bian, Bo, Jin, Xue-Feng, Zhao, Rui, Sun, Caixia, Yuan, Cheng-Yong, Zhou, Yan-Bo, Wu
Publikováno v:
RSC advances. 11(26)
NBe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::ee3dd47ddedab69b12a0442680106e64
https://pubmed.ncbi.nlm.nih.gov/35481175
https://pubmed.ncbi.nlm.nih.gov/35481175
Autor:
Rui, Sun, Xue-Feng, Zhao, Bo, Jin, Bin, Huo, Jian-Hong, Bian, Xiao-Ling, Guan, Caixia, Yuan, Yan-Bo, Wu
Publikováno v:
Physical chemistry chemical physics : PCCP. 22(30)
Computational design has played an important role in planar hyper-coordinate carbon (phC) chemistry. However, none of numerous computationally predicted phC species were subsequently successfully synthesized in the condensed phase, perhaps due to the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::d2580e83921c789d2e1b3810437264f6
https://pubmed.ncbi.nlm.nih.gov/32568316
https://pubmed.ncbi.nlm.nih.gov/32568316
Autor:
Qiang Wang, Yan-Bo Wu, Debao Li, Xiaotai Wang, Fang Huang, Jian-Hong Bian, Ping Liu, Xue-Feng Zhao, Caixia Yuan
Publikováno v:
RSC Advances. 8:36521-36526
The diagonal relationship between beryllium and aluminum and the isoelectronic relationship between BeH unit and Al atom were utilized to design nine new planar and quasi-planar pentacoordinate carbon (ppC) species CAlnBemHxq (n + m = 5, q = 0, ±1,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f23476df7d1aaa8f07ffa8664d63ccd7
https://doi.org/10.1039/c8ra07664b
https://doi.org/10.1039/c8ra07664b
Publikováno v:
Physical Chemistry Chemical Physics. 20:12642-12649
A CB3 moiety extracted from the building units of milestone "hyparenes" (families of species with a planar pentacoordinate carbon (ppC)) was found to be a more basic building block, which can be employed to design a family of "hyparene" analogues CB3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1cb404c30a914162a6de8be72b8a1cc2
https://doi.org/10.1039/c8cp01193a
https://doi.org/10.1039/c8cp01193a