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Akademický článek

Synthesis of a novel phosphate-containing ligand rhodium catalyst and exploration of its optimal reaction conditions and mechanism for the polymerization of phenylacetylene

Autor: Zhang Mingyu, Tang Yuqi, Xu Rui, Yan Dong, Xu Shuangping, Qu Yanqing, Xu Jingyu, Jia Hongge

Publikováno v: Heterocyclic Communications, Vol 29, Iss 1, Pp 67-75 (2023)

Due to the chemical properties of Group VIII transition metals and their importance in catalytic processes, the reactions of rhodium and its neighboring organic complexes have received much attention as model systems. In the present experiments, we s

Externí odkaz: https://doaj.org/article/1c69487e26d14da0b801b05338f524e3

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Akademický článek

Synthesis of rhodium catalysts with amino acid or triazine as a ligand, as well as its polymerization property of phenylacetylene

Autor: Xu Rui, Zhang Mingyu, Zhang Yuyan, Jia Hongge

Publikováno v: Heterocyclic Communications, Vol 28, Iss 1, Pp 149-156 (2022)

Three novel rhodium complexes, with l-tyrosine (l-Tyr), l-arginine (l-Arg), or 2,4-diamino-6-phenyl-1,3,5-triazine (Dpt) as a ligand, named as [Rh(cod)(l-Tyr)], [Rh(cod)(l-Arg)], and [Rh(cod)(Dpt)2], respectively, had been synthesized for catalyzing

Externí odkaz: https://doaj.org/article/6383ebf6135a477e84b36832a45814f6

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Akademický článek

The oxidative coupling between benzaldehyde derivatives and phenylacetylene catalyzed by rhodium complexes via C-H bond activation

Autor: Zhao Xinyi, Jia Hongge, Wang Qingji, Song Heming, Tang Yanan, Ma Liqun, Shi Yongqiang, Yang Guoxing, Wang Yazhen, Zang Yu, Xu Shuangping

Publikováno v: Heterocyclic Communications, Vol 26, Iss 1, Pp 20-25 (2020)

This paper reports the use of rhodium (Rh) catalysts for the oxidative coupling reaction between phenylacetylene and benzaldehyde derivatives via C-H bond activation. These reactions were catalyzed by Rh(l-amino acid)(cod) (the l-amino acid is l-phen

Externí odkaz: https://doaj.org/article/cb5337c3138142c9bae676f668c77998

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