Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Jiří Klicnar"'
Publikováno v:
Collection of Czechoslovak Chemical Communications. 63:793-802
The pKa values of nineteen phenyl hydrazinecarboxylate hydrochlorides R-C6H4OCONHNH2·HCl (R = H, 3- and 4-Cl, 3- and 4-O2N, 4-Me) and their 1-methyl or 2-methyl derivatives were determined by potentiometric titration with tetrabutylammonium hydroxid
Publikováno v:
Collection of Czechoslovak Chemical Communications. 59:2493-2500
1,2,3-Triazolo[1,5-a]- (II) and 1,2,4-triazolo[4,3-a]quinoxaline 5-oxide (III) react with the carbanions of β-diketones and β-keto esters to give enaminones in the same way as their tetrazolo analogue. The difference in mechanism of reactions of th
Publikováno v:
Collection of Czechoslovak Chemical Communications. 58:2121-2127
The title charge-transfer complex crystallizes in the ratio of two molecules of azo dyestuff to one molecule of naphthalene. The crystals are triclinic, space group P1, lattice parameters a = 7.953(1), b = 11.608(2), c = 11.717(2) Å, α = 101.89(2),
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 26
Publikováno v:
Collection of Czechoslovak Chemical Communications. 55:1216-1222
The cyclization reaction kinetics of phenylglyoxal monohydrate with 1,2-diaminobenzene have been studied in formate, acetate, and phosphate buffers. At high pH values and low buffer concentrations the rate-limiting step consists in the protonation of
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :3049-3052
Tetrazolo[1,5-a]quinoxaline-5-oxide 4 reacts with the carbanions of β-diketones and β-keto esters to give enaminoketones and enamino esters, respectively. The N-oxide 4 reacts with 3-methyl- and 3-ethyl-pentane-2,4-dione under similar conditions to
Autor:
Jiří Klicnar, Jaromír Toman
Publikováno v:
Collection of Czechoslovak Chemical Communications. 49:976-983
The paper describes opening of isoxazole ring with 1,2-diaminobenzene leading to 2-cyanomethylene-3-oxo-1,2,3,4-tetrahydroquinoxaline and preparation of its derivatives. Synthesis have been studied of substituted 3,4-dihydro-3-oxo-quinoxaline-oxides,
Publikováno v:
Collection of Czechoslovak Chemical Communications. 42:529-534
Publikováno v:
Collection of Czechoslovak Chemical Communications. 42:3316-3324
Alkaline hydrolysis of (Z)-O-(N-4-nitrophenylcarbamoyl)benzaldoximes (I), the configuration of which was verified by IR spectra, produces a mixture of Z and E-benzaldoximates II and III, benzonitrile IV, and 4-nitrophenylcarbamate ion (V). In subsequ