Výsledky vyhledávání - "Jesus A. Miguel-Garcia"

Olefin uptake as tool for linking platinum(II) and iridium(III) in heterobinuclear complexes: Synthesis and characterization of [PtI2(Me2phen){(C5Me4CH2CH2CHCH2)Ir(Me)(CO)(Ph)}]

Autor: Peter M. Maitlis, Antonella Ciccarese, Paride Papadia, Jesus A. Miguel-Garcia, Francesco Paolo Fanizzi

Publikováno v: Journal of Organometallic Chemistry. 690:2097-2105

The ability of [PtX2(Me2phen)] (Me2phen = 2,9-dimethyl-1,10-phenanthroline, X = Cl, Br, I) to act as olefin scavengers, easily giving stable trigonal bipyramidal five-coordinated platinum species [PtX2(Me2phen)(η2-olefin)], has been checked toward [

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2ae395a58183aaf79ea6016e3ac047b9
https://doi.org/10.1016/j.jorganchem.2005.01.003

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ChemInform Abstract: Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium. A New Route to 1- Substituted 2,3,4,5-Tetramethylcyclopentadienylrhodium Complexes

Autor: Jesus A. Miguel-Garcia, Oleg V. Gusev, Arkady Z. Rubezhov, Peter M. Maitlis

Publikováno v: ChemInform. 22

Reaction of [Rh(C5Me5)(C5H5)]+ with KOBut in tetrahydrofuran gives [Rh(C5Me4CH2)(C5H5)]; it reacts readily with halides (R—X) to give [Rh(C5Me4CH2R)(C5H5)]X, which can be converted into [Rh2(C5Me4CH2R)2Cl4].

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::368f953d6c6c2033b72a977cfb88290f
https://doi.org/10.1002/chin.199135229

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Ring-methyl activation in pentamethylcyclopentadienyliridium complexes; synthesis of [(C5Me4CH2E)IrLn] (E = SiMe3, PhCH2, CH2=CHCH2, PPh2, and Pt(PEt3)2Cl), and synthesis and X-ray structure of [(1,3-C5Me3(CH2SiMe3)2)Ir(CO)Me(Cl)]

Autor: Neil A. Beiley, Jesus A. Miguel-Garcia, Harry Adams, Peter M. Maitlis

Publikováno v: Journal of Organometallic Chemistry. 413:427-444

The pentamethylcyclopentadienyliridium complex [C 5 Me 5 Ir(Me)CO(Ph)] ( 1 ) is metallated by Sec-BuLi at a ring methyl. The lithio-complex intermediate, presumably Li[(C 5 Me 4 CH 2 )Ir(Me)CO(Ph)] ( 2 ) reacts with various halides (E–X) to give th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::44dd750b280c043557dba19be0066953
https://doi.org/10.1016/0022-328x(91)80068-u

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Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes

Autor: Jesus A. Miguel-Garcia, Peter M. Maitlis, Oleg V. Gusev, Arkady Z. Rubezhov

Publikováno v: Mendeleev Communications. 1:21-22

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b4e7e16a50b6598cfe6c30bf9ade99db
https://doi.org/10.1070/mc1991v001n01abeh000013

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Ring-methyl activation in pentamethylcyclopentadienyliridium complexes. Part 2. Synthesis of C5Me4(functionalized alkyl) complexes and crystal structures of [(C5Me4CH2CPh2OH)-IrMe(CO)Ph] and [(C5Me4CH2CO2H)IrMe(CO)Cl]

Autor: Jesus A. Miguel-Garcia, Peter M. Maitlis, Harry Adams, Neil A. Bailey

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :131

Reaction of [(C5Me5)IrMe(CO)Ph]1 with sec-butyllithium gives a lithio complex, presumably Li[(C5Me4CH2)IrMe(CO)Ph]2, which reacts with PhCOR to give the appropriately substituted [{C5Me4CH2CPh(OH)R}IrMe(CO)Ph]3a(R = Me) and 3b(R = Ph). Hydrogen chlor

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fec0dbdfb33d71e728850b3094e6a70a
https://doi.org/10.1039/dt9920000131

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Activation of ring methyls in pentamethylcyclopentadienyliridium(III); new routes to functionalised complexes

Autor: Peter M. Maitlis, Jesus A. Miguel-Garcia

Publikováno v: Journal of the Chemical Society, Chemical Communications. :1472

Pentamethylcyclopentadienyliridium(III) complexes, e.g.[(C5Me4CH3)Ir(Me)(Ph)(CO)] are metallated by BusLi at a ring methyl; the resultant lithio-complex reacts with organic halides, ketones and CO2 to give the appropriately substituted [(C5Me4CH2W)Ir

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3fce3246a0881047ce4ab7493ca6fff2
https://doi.org/10.1039/c39900001472

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