Shedding Light on the Photochemistry of Coinage-Metal Phosphorescent Materials: A Time-Resolved Laue Diffraction Study of an AgI–CuI Tetranuclear Complex

Autor: Katarzyna N. Jarzembska, Jesse D. Sokolow, Philip Coppens, Radosław Kamiński, Yang Chen, Robert Henning, Elzbieta Trzop, Bertrand Fournier

Publikováno v: Inorganic Chemistry. 53:10594-10601

The triplet excited state of a new crystalline form of a tetranuclear coordination d(10)-d(10)-type complex, Ag2Cu2L4 (L = 2-diphenylphosphino-3-methylindole ligand), containing Ag(I) and Cu(I) metal centers has been explored using the Laue pump-prob

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2c158674e471e8e63bd514487488f438
https://doi.org/10.1021/ic501696y

A Large Manganese‐doped Polyoxotitanate Nanocluster: Ti 14 MnO 14 (OH) 2 (OEt) 28

Autor: Yu-Sheng Chen, Jesse D. Sokolow, Yang Chen, Philip Coppens, Elzbieta Trzop

Publikováno v: Journal of the Chinese Chemical Society. 60:887-890

A large manganese-doped polyoxotitanate nanocluster, Ti14MnO14(OH)2(OEt)28, has been synthesized under solvothermal conditions. Its structure is similar to previously reported Ti17O24(O i Pr)20, but lacks 5-fold coordinated Ti atoms which are potenti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cd44b71700ffd3797c9743269c3cf449
https://doi.org/10.1002/jccs.201300163

Nanosized alkali-metal-doped ethoxotitanate clusters

Autor: Elzbieta Trzop, Jesse D. Sokolow, Philip Coppens, Anna Makal, Yang Chen

Publikováno v: Inorganic chemistry. 52(9)

The synthesis and crystallographic characterization of alkali-metal-doped ethoxotitanate clusters with 28 and 29 Ti atoms as well as a new dopant-free Ti28 cluster are presented. The light-metal-doped polyoxotitanate clusters in which the alkali-meta

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https://pubmed.ncbi.nlm.nih.gov/23587091

Restricted Photochemistry in the Molecular Solid State: Structural changes on Photoexcitation of Cu(I) Phenanthroline metal-to-ligand-charge-transfer (MLCT) complexes by Time-Resolved Diffraction

Autor: Tim Graber, Philip Coppens, Jason B. Benedict, Jarosław A. Kalinowski, Yang Chen, Anna Makal, Elzbieta Trzop, Bertrand Fournier, Jesse D. Sokolow, Robert Henning

The excited-state structure of [Cu(I)[(1,10-phenanthroline-N,N') bis(triphenylphosphine)] cations in their crystalline [BF(4)] salt has been determined at both 180 and 90 K by single-pulse time-resolved synchrotron experiments with the modified polyc

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https://europepmc.org/articles/PMC3545449/

Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2 ·BPh4

Autor: Philip Coppens, Anna Makal, Tim Graber, Jesse D. Sokolow, Robert Henning, Stephan Scheins, Elzbieta Trzop, Jason B. Benedict

Publikováno v: Benedict, J B, Makal, A, Sokolow, J D, Trzop, E, Scheins, S, Henning, R, Graber, T & Coppens, P 2011, ' Time-resolved Laue diffraction of excited species at atomic resolution : 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh(2)(mu-PNP)(2)(PNP)(2)center dot BPh(4) ', Chemical Communications, vol. 47, no. 6, pp. 1704-1706 . https://doi.org/10.1039/c0cc04997b

The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump–probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh–Rh distance of 0.154 (13) A is less than predicted

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc6b79524fc7b3944a473ccc6f9d67cd
https://europepmc.org/articles/PMC3129623/