Gas-Phase C−H and N−H Bond Activation by a High Valent Nitrido-Iron Dication and 〈NH〉-Transfer to Activated Olefins

Autor: Markus Reiher, Detlef Schröder, Johannes Neugebauer, Andreas Grohmann, Frank W. Heinemann, Helmut Schwarz, Jesús Pitarch López, Maria Schlangen, Marco Haryono

Publikováno v: Journal of the American Chemical Society. 130:4285-4294

A tetrapodal pentadentate nitrogen ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) is used for the synthesis of the azido-iron(III) complex [(1)Fe(N3)]X2 where X is either Br or PF6. By means of electrospray ionization mass spectrometry, the di

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::34cc46c5ad315c6a9f3fdcf76920bfcc
https://doi.org/10.1021/ja075617w

Alternating perpendicular 1-D channels in the supramolecular structure of the copper(II) complex [Cu(pyterpy)2](PF6)2·CH3OH·0.5 CH2Cl2 (pyterpy=4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine)

Autor: Andreas F. Thünemann, Günter Reck, Werner Kraus, Dirk G. Kurth, Jesús Pitarch López

Publikováno v: Inorganic Chemistry Communications. 8:281-284

The reaction of 4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine (pyterpy) with copper(II) yields the novel mononuclear [Cu(pyterpy) 2 ](PF 6 ) 2 complex. The crystal structure shows that the Cu(II) center is coordinated by the terpyridine d

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::14ffba520fb516f429aea482fa0de8ef
https://doi.org/10.1016/j.inoche.2004.12.030

Unusual oxidative stability of a multidentate primary amine ligand: facile synthesis of the oxo-bridged diiron(III) complex

Autor: Gadde Ramachandraiah, Olivier Horner, Jesús Pitarch López, Frank W. Heinemann, Andreas Grohmann, Jean-Mare Latour

Publikováno v: Inorganic Chemistry Communications
Inorganic Chemistry Communications, Elsevier, 2004, 7, pp.773-776. ⟨10.1016/j.inoche.2004.03.026⟩
Inorganic Chemistry Communications, 2004, 7, pp.773-776. ⟨10.1016/j.inoche.2004.03.026⟩

International audience; The tetrapodal pentaamine 2,6-C5H3N[CMe(CH2NH2)2]2 (pyN4, 1), which possesses four equivalent primary amino groups, has been used to prepare the diiron(III) oxo complex [(1)2Fe2(μ2-O)](ClO4)4(2), by aerobic oxidation of the m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::756e7d4632a6c39a9f1797c926b84f1e
https://doi.org/10.1016/j.inoche.2004.03.026

A new Co(ii)-metalloviologen-based electrochromic material integrated in thin multilayer films

Autor: Jesús Pitarch López, Wen-Fei Dong, Dirk G. Kurth

Publikováno v: Chem. Commun.. :2119-2121

A metallosupramolecular coordination polyelectrolyte prepared by the reaction of cobalt(II) with a novel bisterpyridine ligand has been assembled as the active component in electrochromic films by sequential deposition using electrostatic layer-by-la

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7d5507494c7cf469fb6c08261d025982
https://doi.org/10.1039/b500994d

Iron carbonyl, nitrosyl, and nitro complexes of a tetrapodal pentadentate amine ligand: synthesis, electronic structure, and nitrite reductase-like reactivity

Autor: Jean-Marc Latour, Raju Prakash, Jesús Pitarch López, Frank W. Heinemann, Andreas Grohmann, Jean-Louis Oddou, Claudine Jeandey, Bernd A. Hess, Olivier Horner

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 8(24)

The tetrapodal pentaamine 2,6-C5H3N[CMe(CH2NH2)2]2 (pyN4, 1) forms a series of octahedral iron(II) complexes of general formula [Fe(L)(1)]Xn with a variety of small-molecule ligands L at the sixth coordination site (L = X = Br, n = 1 (2); L = CO, X =

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c38bcd96c22c280102a08933ce1e74af
https://pubmed.ncbi.nlm.nih.gov/12693053