Hydrogenation of β- N-substituted enaminoesters in the presence of ruthenium catalysts

Autor: Hebbache, Hania, Jerphagnon, Thomas, Hank, Zakia, Bruneau, Christian, Renaud, Jean-Luc

Publikováno v: In Journal of Organometallic Chemistry 2010 695(6):870-874

Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation

Autor: Jerphagnon, Thomas, Renaud, Jean-Luc, Bruneau, Christian

Publikováno v: In Tetrahedron: Asymmetry 2004 15(14):2101-2111

Ruthenacycles and Iridacycles as Catalysts for Asymmetric Transfer Hydrogenation and Racemisation.

Autor: Jerphagnon, Thomas¹, Haak, Robert¹, Berthiol, Florian¹, Gayet, Arnaud J. A.¹, Ritleng, Vincent^1,2, Holuigue, Alexandre^2,3, Pannetier, Nicolas³, Pfeffer, Michel³, Voelklin, Adeline², Lefort, Laurent², Verzijl, Gerard², Tarabiono, Chiara⁴, Janssen, Dick B.⁴, Minnaard, Adriaan J.¹, Feringa, Ben L.¹, de Vries, Johannes G.² Hans-JG.Vries-de@dsm.com

Publikováno v: Topics in Catalysis. Sep2010, Vol. 53 Issue 15-18, p1002-1008. 7p. 7 Diagrams, 4 Charts, 1 Graph.

Fast racemisation of chiral amines and alcohols by using cationic half-sandwich ruthena- and iridacycle catalysts

Autor: Jerphagnon, Thomas, Gayet, Arnaud J. A., Berthiol, Florian, Ritleng, Vincent, Mrsic, Natasa, Meetsma, Auke, Pfeffer, Michel, Minnaard, Adriaan J., Feringa, Ben L., de Vries, Johannes G., Mršić, Nataša

Publikováno v: Chemistry, 15(46), 12780-12790. Wiley-VCH Verlag GmbH & Co. KGaA
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2009, 15 (46), pp.12780-12790. ⟨10.1002/chem.200902103⟩

The lipase-catalysed resolution of alcohols and amines yields only 50% of the desired enantiopure product. However, addition of a racemisation catalyst leads to 100% yield in what is called a dynamic kinetic resolution (DKR). There is a need for new

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3a7c060624d85305817f4d04b6171fb5
https://research.rug.nl/en/publications/78e9a314-1466-4e60-a891-82e24bfa4459

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