Výsledky vyhledávání - "Jeroen Rintjema"

Akademický článek

Biobased Terpene Derivatives: Stiff and Biocompatible Compounds to Tune Biodegradability and Properties of Poly(butylene succinate)

Autor: Reza Zeinali, Luis J. del Valle, Lourdes Franco, Ibraheem Yousef, Jeroen Rintjema, Carlos Alemán, Fernando Bravo, Arjan W. Kleij, Jordi Puiggalí

Publikováno v: Polymers, Vol 14, Iss 1, p 161 (2021)

Different copolymers incorporating terpene oxide units (e.g., limonene oxide) have been evaluated considering thermal properties, degradability, and biocompatibility. Thus, polycarbonates and polyesters derived from aromatic, monocyclic and bicyclic

Externí odkaz: https://doaj.org/article/d498f98de5dd4e6da6305f08403b7aa2

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Deciphering the Keys for High Enantioselectivity in Hypervalent Iodine-Catalyzed 1,2-Difunctionalization: Improved Synthesis of Ishihara–Muñiz Precatalysts

Autor: Fernando Bravo, Kilian Muñiz, Eric Cots, Jeroen Rintjema

Publikováno v: Organic Letters. 23:6429-6434

In the course of upscaling the synthesis of enantiopure aryliodine precatalysts, we detected an unreported meso form of the catalysts for the first time. A new scalable route was developed to avoid epimerization of the lactamide arms, providing synth

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::22e4880749a6158c5b26776e0ded8cee
https://doi.org/10.1021/acs.orglett.1c02252

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A biosourced epoxy resin for adhesive thermoset applications

Autor: Vitor B. Moreira, Carlos Alemán, Jeroen Rintjema, Fernando Bravo, Arjan W. Kleij, Elaine Armelin

Publikováno v: UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)

Biobased epoxy-derived raw materials will be essential for future coating and adhesive designs in industry. Here, a facile approach is reported towards the incorporation of limonene into an epoxy-functionalized polycarbonate and its crosslinking with

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e59f2638be467426949ca9c15020df35
https://hdl.handle.net/2117/370210

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Novel Biobased Epoxy Thermosets and Coatings from Poly(limonene carbonate) Oxide and Synthetic Hardeners

Autor: Vitor Bonamigo Moreira, Jeroen Rintjema, Fernando Bravo, Arjan W. Kleij, Lourdes Franco, Jordi Puiggalí, Carlos Alemán, Elaine Armelin

Publikováno v: UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)

In the area of coating development, it is extremely difficult to find a substitute for bisphenol A diglycidyl ether (DGEBA), the classical petroleum-based raw material used for the formulation of epoxy thermosets. This epoxy resin offers fast curing

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::76d0dfd53a74c7ec5474083b49c4fc6b
https://pubmed.ncbi.nlm.nih.gov/35360277

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Deciphering key intermediates in the transformation of carbon dioxide into heterocyclic products

Autor: Eduardo C. Escudero-Adán, Atsushi Urakawa, Arjan W. Kleij, Carles Bo, Eddy Martin, Joan González-Fabra, Jeroen Rintjema, Rui Huang

Publikováno v: RECERCAT (Dipòsit de la Recerca de Catalunya)
Recercat. Dipósit de la Recerca de Catalunya
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The identification of catalytic intermediates in the conversion of carbon dioxide is vital for improved catalyst design and optimization of structure–reactivity relationships, but remains elusive. Here, we report that intermolecular hydrogen bondin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::131827167ce25eba0c24e4c5ebd1d094
http://hdl.handle.net/2072/352782

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Vanadium(V) Catalysts with High Activity for the Coupling of Epoxides and CO2: Characterization of a Putative Catalytic Intermediate

Autor: Cristiano Zonta, Giulia Licini, Jeroen Rintjema, Claudia Miceli, Arjan W. Kleij, Eddy Martin, Eduardo C. Escudero-Adán

Publikováno v: RECERCAT (Dipòsit de la Recerca de Catalunya)
Recercat. Dipósit de la Recerca de Catalunya
instname

Vanadium(V) complexes derived from aminotriphenolate ligands are demonstrated to be highly active catalysts for the coupling of various terminal and internal epoxides with carbon dioxide to afford a series of substituted organic carbonates in good yi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::226d91037edadbc1ba50a241ffda4ba7
http://hdl.handle.net/11577/3227901

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Aluminum-Mediated Formation of Cyclic Carbonates: Benchmarking Catalytic Performance Metrics

Autor: Jeroen Rintjema, Arjan W. Kleij

Publikováno v: RECERCAT (Dipòsit de la Recerca de Catalunya)
Recercat. Dipósit de la Recerca de Catalunya
instname

We report a comparative study on the activity of a series of fifteen binary catalysts derived from various reported aluminum-based complexes. A benchmarking of their initial rates in the coupling of various terminal and internal epoxides in the prese

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ae7dd1c2af5fd59714b6e9ccb298371e
https://pubmed.ncbi.nlm.nih.gov/27922208

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ChemInform Abstract: Catalytic One-Pot Oxetane to Carbamate Conversions: Formal Synthesis of Drug Relevant Molecules

Autor: Wusheng Guo, Victor Laserna, Jeroen Rintjema, Arjan W. Kleij

Publikováno v: ChemInform. 47

Oxetanes are versatile building blocks in drug-related synthesis to induce property-modulating effects. Whereas related oxiranes are widely used in coupling chemistry with carbon dioxide (CO2) to afford value-added commodity chemicals, oxetane/CO2 co

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8c8442a5f11c20003dc59421316fd8d4
https://doi.org/10.1002/chin.201639064

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ChemInform Abstract: Substrate-Controlled Product Divergence: Conversion of CO2into Heterocyclic Products

Autor: Eddy Martin, Eduardo C. Escudero-Adán, Roel Epping, Jeroen Rintjema, Arjan W. Kleij, Giulia Fiorani

Publikováno v: ChemInform. 47

Substituted epoxy alcohols and amines allow substrate-controlled conversion of CO2 into a wide range of heterocyclic structures through different mechanistic manifolds. This new approach results in an unusual scope of CO2-derived products by initial

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0edef8cd027a9fb558ee8e31b8cb1b91
https://doi.org/10.1002/chin.201630149

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Catalytic One-Pot Oxetane to Carbamate Conversions: Formal Synthesis of Drug Relevant Molecules

Autor: Wusheng Guo, Jeroen Rintjema, Arjan W. Kleij, Victor Laserna

Publikováno v: RECERCAT (Dipòsit de la Recerca de Catalunya)
Recercat. Dipósit de la Recerca de Catalunya
instname

Oxetanes are versatile building blocks in drug- related synthesis to induce property-modulating effects. Whereas related oxiranes are widely used in coupling chemistry with carbon dioxide (CO2) to afford value-added commodity chemicals, oxetanes/CO2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c0d3fb8ccc0111e62425e908df0aa802
https://hdl.handle.net/2072/356053

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