Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Jeremy L. Bourque"'
Autor:
Jeremy L. Bourque, Stephen J. Geier, Christopher M. Vogels, Andreas Decken, Stephen A. Westcott
Publikováno v:
Crystals, Vol 5, Iss 1, Pp 91-99 (2015)
Reductive amination of salicylaldehyde or 3,5-di-tert-butylsalicylaldehyde and 1-adamantylamine using NaBH4 gave the corresponding aminoalcohols in high yields. Subsequent addition of one equivalent of H3B·SMe2 to the aminoalcohols, with loss of two
Externí odkaz:
https://doaj.org/article/d172f2e6bc7445099f8f5abba235cbf6
Autor:
Jeremy L. Bourque, Kim M. Baines
Publikováno v:
IUCrData, Vol 1, Iss 3, p x160370 (2016)
The structure of tetramethylammonium trifluoromethanesulfonate, C4H12N+·CF3SO3−, was determined at 110 K in the monoclinic space group P21/m. The salt, which contains two cations and two anions in the asymmetric unit, has a network structure displ
Externí odkaz:
https://doaj.org/article/f5af4877d2084aa1a62e473c2ee5ab1d
Publikováno v:
IUCrData, Vol 1, Iss 3, p x160389 (2016)
The crystal structure of (tert-butyl isocyanide-κC)trichloridogallium(III), [GaCl3(C5H9N)], features the first reported isocyanide–gallium trihalide complex. The Ga—C—N—C fragment is essentially linear. The methyl fragments of the tert-butyl
Externí odkaz:
https://doaj.org/article/e30d24fb531243e9b9613ab999ab14b7
Autor:
Maissa P. Belcina, Bahareh Farhadpour, Nada Y. Tashkandi, Andrew T. Henry, Jeremy L. Bourque, Kim M. Baines
Publikováno v:
Canadian Journal of Chemistry. 101:126-132
The addition of secondary phosphine oxides to tetramesityldisilene and tetramesityldigermene results in the mild, partial reduction of the P(V) centre of the organophosphorus oxide to P(III) to yield disilyl and digermyl phosphinite derivatives and i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b639f6d7c38e0b152a6435f6f5cac63e
https://doi.org/10.1139/cjc-2021-0331
https://doi.org/10.1139/cjc-2021-0331
Autor:
Jeremy L. Bourque, Kim M. Baines
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 649
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::63da4cd9980813a71f3692467cbb9685
https://doi.org/10.1002/zaac.202200360
https://doi.org/10.1002/zaac.202200360
Publikováno v:
Inorganic Chemistry. 60:14713-14720
The synthesis and reactivity of a gallium(I) cationic complex using [12]crown-4 as a stabilizing ligand were explored. The synthesis of [Ga([12]crown-4)][GaCl4] was achieved in one step from commercially available starting materials. Anion exchange w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e10b346116e8cef0c912cfc356f74273
https://doi.org/10.1021/acs.inorgchem.1c01801
https://doi.org/10.1021/acs.inorgchem.1c01801
Publikováno v:
Chemistry Publications
The addition of (2-ethynyl-3-methoxy-2-methylcyclopropyl)benzene to Tip Si=SiTipPh, a disilene with an asymmetric substitution pattern, was investigated. The regiochemistry of the ring-opened products indicates a stepwise mechanism with a biradical i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8277d27e8a48ad5d39466973d8c68390
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 50(47)
The NH bond activation of ammonia, primary and secondary amines by tetramesityldisilene and -digermene was investigated. In each case, a disilyl- or digermylamine was formed as the only product of amine addition. The mechanism of the addition of ammo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f7167b25795cee046508087536d97e9
https://pubmed.ncbi.nlm.nih.gov/34812813
https://pubmed.ncbi.nlm.nih.gov/34812813
Publikováno v:
Chemistry Publications
The addition of 2,6-dimethylphenyl isocyanide and t-butyl isocyanide to tetramesityldisilene was examined. In both cases, the initially formed product is an iminodisilirane; however, the iminodisiliranes are unstable under the reaction conditions and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4f27c4cf26f77202c2d96c0ae2338239
https://doi.org/10.1002/anie.201808490
https://doi.org/10.1002/anie.201808490
Publikováno v:
Chemistry Publications
The electronic structures of a series of gallium complexes are examined using X-ray absorption spectroscopy (XAS) in combination with ab initio calculations. The chemical states of Ga are strongly affected by the ligands and the bonding environment.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3057841ca8d09cd5762ebb78d8e07df0
https://doi.org/10.1021/acs.inorgchem.6b03083
https://doi.org/10.1021/acs.inorgchem.6b03083