Electronically-coupled redox centers in trimetallic cobalt complexes

Autor: Jeremy A. Intrator, Nicholas M. Orchanian, Andrew J. Clough, Ralf Haiges, Smaranda C. Marinescu

Publikováno v: Dalton Transactions. 51:5660-5672

Synthesis and isolation of molecular building blocks of metal-organic frameworks (MOFs) can provide unique opportunities for characterization that would otherwise be inaccessible due to the heterogeneous nature of MOFs. Herein, we report a series of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3a8cbabc161788597625cb8d51156d6a
https://doi.org/10.1039/d1dt03404a

Isotope Effects Reveal an Alternative Mechanism for 'Iminium-Ion' Catalysis

Autor: Jeremy A Intrator, Pernille H. Poulsen, Mathew J. Vetticatt, Karl Anker Jørgensen, Joseph A. Izzo

Publikováno v: Izzo, J A, Poulsen, P H, Intrator, J A, Jørgensen, K A & Vetticatt, M J 2018, ' Isotope Effects Reveal an Alternative Mechanism for "iminium-Ion" Catalysis ', Journal of the American Chemical Society, vol. 140, no. 27, pp. 8396-8400 . https://doi.org/10.1021/jacs.8b04856

A novel mechanism for the epoxidation of enals with hydrogen peroxide catalyzed by diarylprolinol silyl ether supported by experimental 13C kinetic isotope effects (KIEs) and density functional theory calculations is presented. Normal 13C KIEs, measu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3dd40e5622c9166a539b43527c502a51
https://doi.org/10.1021/jacs.8b04856