Understanding the Interplay of Vacancy, Cation, and Charge Ordering in the Tunable Sc2VO5+δ Defect Fluorite System

Autor: Jenny R Panchuk, Christopher R. Wiebe, Cole Mauws, Dmitry Vrublevskiy, Joey A. Lussier, Jeremiah C. Beam, Andrew P. Grosvenor, Mario Bieringer

Publikováno v: Inorganic Chemistry. 60:872-882

We report the synthesis, structure, and redox behavior of the cation-ordered tetragonal Sc2VO5+δ defect fluorite superstructure previously thought to be the oxygen precise A3+2B4+O5 phase. Four synthesis routes in oxidative, reductive, and inert atm

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::97a4caf5935d14a8794026bcead6ff7c
https://doi.org/10.1021/acs.inorgchem.0c02992

List of contributors

Autor: T. Alejo, A.C. Bastos, A.D. Batako, Jeremiah C. Beam, Camillo Benetti, Dino N. Boccaccini, Ju. I. Bublikov, Maria Cannio, J.L. Castro-Mayorga, Paolo Colombo, Hailin Cong, Suman Kalyan Das, C. Drosos, Fuyuaki Endo, M.J. Fabra, M.G.S. Ferreira, B.K.C. Ganesh, L.G. Gómez-Mascaraque, D. Gopi, S.N. Grigoriev, B. Grünler, Andrew G. Harris, A. Heft, Atsushi Hotta, Borislav L. Ivanov, A. Karthika, L. Kavitha, John A. Kozub, B.S.M. Kretzschmar, S. Anand Kumar, Volodymyr Kyryliv, Cristina Leonelli, D. López-Díaz, A. López-Rubio, Charles M. Lukehart, Tomoki Maeda, Boris Mahltig, Tithi Maity, Olha Maksymiv, B. Martín-García, Qingye Meng, M.D. Merchán, Hryhoriy Nykyforchyn, I.P. Parkin, Chiara Ponzoni, Prasanta Sahoo, Bidhan Chandra Samanta, R. Sánchez-Hidalgo, A. Schimanski, J. Schmidt, A.E. Seleznev, N.N. Sitnikov, E.S. Sotova, J. Tedim, Torsten Textor, Kazuhisa Tsuji, M.M. Velázquez, A.A. Vereschaka, D. Vernardou, M.A. Volosova, Yuezhong Wang, Matthew S. Wellons, Tin Wui Wong, Xiaodan Xu, Bing Yu, Hua Yuan, Feng Zhai, I. Zunke, Olha Zvirko

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::975e116f42eda6e91fc77eff316e39f1
https://doi.org/10.1016/b978-0-444-63240-1.00022-x

Understanding the Interplay of Vacancy, Cation, and Charge Ordering in the Tunable Sc

Autor: Dmitry, Vrublevskiy, Joey A, Lussier, Jenny R, Panchuk, Cole, Mauws, Jeremiah C, Beam, Christopher R, Wiebe, Andrew P, Grosvenor, Mario, Bieringer

Publikováno v: Inorganic chemistry. 60(2)

We report the synthesis, structure, and redox behavior of the cation-ordered tetragonal Sc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::d1473cbc8156bdf40c97d0b1ea4eacd5
https://pubmed.ncbi.nlm.nih.gov/33355450

Investigation of Factors That Affect the Oxidation State of Ce in the Garnet-Type Structure

Autor: Rahin Sifat, Andrew P. Grosvenor, Jeremiah C. Beam

Publikováno v: Inorganic chemistry. 58(4)

Oxide materials that adopt the garnet-type structure (X3A2B3O12) have received attention for a wide variety of applications, one of which is as potential wasteforms for the sequestration of radioactive actinide elements. The actinides are able to be

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::07ced9c9970a06462b2a4e3559e9463e
https://pubmed.ncbi.nlm.nih.gov/30698434

An X-ray spectromicroscopy study of the calcium mineralization in the JEB tailings management facility at McClean Lake, Saskatchewan

Autor: Andrew M. Crawford, Kebbi A. Hughes, John Rowson, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm, Joseph Essilfie-Dughan

Publikováno v: Applied Geochemistry. 112:104459

Solid mine/mill waste, known as tailings, often contain trace chemical species of interest that cannot be easily identified using bulk analysis methods. Existing methodologies for the identification of trace chemical species within heterogeneous mate

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bd6f23a963b40b0bfff04ec2a78f9335
https://doi.org/10.1016/j.apgeochem.2019.104459