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Molecular studies of the initiation and termination steps of the anionic polymerization of P=C bonds
Autor:
Justin J. Kingsley, Tom H. H. Hsieh, Bastian Feldscher, Jennifer M. Wissenz, Bronwyn H. Gillon, Zhi Ming Kam, Derek P. Gates, Kevin J. T. Noonan, Joshua I. Bates
Publikováno v:
Canadian Journal of Chemistry. 85:1045-1052
The initiation and termination steps of the anionic polymerization of P=C bonds have been modeled. The initiation step was investigated through the stoichiometric reaction of MesP=CPh2 (1) with RLi (R = Me or n-Bu). In each case, the addition was hig