Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Jennifer L. Caldarelli"'
Publikováno v:
Angewandte Chemie International Edition. 37:2093-2096
Facile displacement of the ether ligand from complex 1 provides a convenient route to the reactive cation [WTp'(CO)(PhC≡CMe)]+ (Tp'=hydridotris(3,5-dimethylpyrazol-1-yl)borate). In the absence of suitable ligands, 1 decomposes in dichloromethane an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c9ee1e2b2b6ea9bcde9666b07190c07d
https://doi.org/10.1002/(sici)1521-3773(19980817)37:15<2093::aid-anie2093>3.0.co
https://doi.org/10.1002/(sici)1521-3773(19980817)37:15<2093::aid-anie2093>3.0.co
Publikováno v:
Angewandte Chemie. 110:2207-2210
Leicht abspalten last sich der Etherligand aus dem Komplex 1 und ermoglicht damit einen Zugang zu dem reaktiven Kation [WTp′(CO)(PhC≡CMe)]+ (Tp′=Hydridotris(3,5-dimethylpyrazol-1-ylborat). In Dichlormethan zerfallt 1 in Abwesenheit potentieller
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::899045d5fbbe5914f66cfa15df1b463a
https://doi.org/10.1002/(sici)1521-3757(19980803)110:15<2207::aid-ange2207>3.0.co
https://doi.org/10.1002/(sici)1521-3757(19980803)110:15<2207::aid-ange2207>3.0.co
Autor:
B. E. Woodworth, S. G. Feng, Michael B. Wells, Joseph L. Templeton, Jennifer L. Caldarelli, Craig C. Philipp, Peter S. White
Publikováno v:
Journal of Organometallic Chemistry. 478:103-110
Molecular orbital descriptions for five closely related cis -dicarbonyl tungsten(II) d b4 model complexes are presented. The idealized compounds considered are [H 3 W(CO) 2 (SH) 2− , [H 3 W(CO) 2 (OH) 2− , [H 3 W(CO) 2 (NH 2 )] 2− , [H 3 W(CO)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b328175fc7ddd85edce08834e88d9b35
https://doi.org/10.1016/0022-328x(94)88162-6
https://doi.org/10.1016/0022-328x(94)88162-6
Publikováno v:
Journal of the American Chemical Society. 116:2878-2888
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::efc9eced6fa0d050636482de1b306c37
https://doi.org/10.1021/ja00086a021
https://doi.org/10.1021/ja00086a021
Publikováno v:
Journal of the American Chemical Society. 114:10097-10103
Displacement of a carbonyl ligand from a cationic dicarbonyltungsten complex, [Tp'W(CO) 2 (PhC≡Me)] [X] (Tp'= hydridotris(3,5-dimethylpyrazolyl)borate; X=BF 4 - , PF 6 - , and OTS), by the counterion is effected by allowing the complex to reflux in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::11845d74dd5b104146b673b528e67eb2
https://doi.org/10.1021/ja00052a001
https://doi.org/10.1021/ja00052a001
Publikováno v:
Angewandte Chemie (International ed. in English). 37(15)
Facile displacement of the ether ligand from complex 1 provides a convenient route to the reactive cation [WTp'(CO)(PhC≡CMe)]
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::d110a5fa2bb434ee2be77fe836f527f5
https://pubmed.ncbi.nlm.nih.gov/29711042
https://pubmed.ncbi.nlm.nih.gov/29711042