Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Jennifer D. Draper"'
Publikováno v:
Inorganic Chemistry. 38:1356-1359
Zinc(II) and cadmium(II) salts of the formula [K(THF)6][M(O-2,6-tBu2C6H3)3] have been synthesized and fully characterized. The K cation, solvated by THF molecules, has no interaction with the trigonal-planar group 12 metal anion. The zinc complex exh
Autor:
Jeffrey B. Robertson, Ginette E. Struck, Sharon A. Niezgoda, Patrick Rainey, Matthew W. Holtcamp, Joseph H. Reibenspies, Marc Zimmer, Donald J. Darensbourg, Jennifer D. Draper
Publikováno v:
Journal of the American Chemical Society. 121:107-116
A series of zinc phenoxides of the general formula (2,6-R2C6H3O)2Zn(base)2 [R = Ph, tBu, iPr, base = Et2O, THF, or propylene carbonate] and (2,4,6-Me3C6H2O)2Zn(pyridine)2 have been synthesized and characterized in the solid state by X-ray crystallogr
Publikováno v:
Inorganic Chemistry. 37:5383-5386
The synthesis and spectroscopic (13C NMR, IR) characterization of two zerovalent metal carbonyl complexes incorporating the tetradentate ligand salen have been accomplished. IR and 13C NMR studies ...
Autor:
Jeffrey C. Yoder, Joseph H. Reibenspies, Ginette E. Struck, Donald J. Darensbourg, Jennifer D. Draper, Matthew W. Holtcamp
Publikováno v:
Inorganica Chimica Acta. 274:115-121
The addition of Na(2,6-diphenylphenoxide) to a diethyl ether solution of the monomeric Zn(2,6-diphenylphenoxide)2(THF)2 derivative affords the trisphenoxide complex, Na[Zn(2,6-diphenylphenoxide)3(H2O)] (1). An X-ray crystal structure analysis of 1 re
Autor:
David L. Larkins, Joseph H. Reibenspies, Jennifer D. Draper, Donald J. Darensbourg, Brian J. Frost
Publikováno v:
Inorganic Chemistry. 37:2538-2546
of M(CO)5THF with the tetraethylammonium salt of the corresponding acid or uracil. These complexes have been characterized in solution by IR and 13C NMR spectroscopy and in the solid state by X-ray crystallography. The geometry of the metal dianions
Autor:
Joseph H. Reibenspies, Jennifer A. Chojnacki, Kevin K. Klausmeyer, Donald J. Darensbourg, Jennifer D. Draper
Publikováno v:
Inorganica Chimica Acta. 270:405-413
The complex [Et4N][W(CO)5OMe] (1) has been prepared from the reaction of the photochemically generated W(CO)5THF adduct and [Et4N][OH] in methanol. Complex 1 was shown to undergo rapid CO dissociation in THF to quantitatively provide the dimeric dian
Autor:
Ferenc Joó, Ágnes Kathó, Nicole White Stafford, Joseph H. Reibenspies, Jeffrey B. Robertson, Jennifer D. Draper, Tara J. Decuir, Donald J. Darensbourg
Publikováno v:
Inorganic Chemistry. 36:4218-4226
The syntheses of a variety of group 10 metal complexes of the water-soluble phosphine triazaphosphaadamantane (PTA) are described. Treatment of Ni(NO3)2 with NaNO2 and PTA provides the nitrosyl complex [Ni(NO)(PTA)3]NO3 (1). Complex 1 is soluble in w
Autor:
Donald J. Darensbourg, Matthew W. Holtcamp, Jennifer D. Draper, Sharon A. Niezgoda, Joseph H. Reibenspies
Publikováno v:
Inorganic Chemistry. 36:2426-2432
A synthetic methodology for the preparation of a large variety of eta(3)-HB(3-Phpz)(3)Cd(acetate) adducts is presented which involves replacement of toluene in the eta(3)-HB(3-Phpz)(3)Cd(acetate) solvate complex by the appropriate cyclic ether or cyc
Publikováno v:
Inorganic Chemistry. 36:5686-5688
Three monomeric Cd(II) phenoxide complexes have been prepared by reacting Cd[N(SiMe(3))(2)](2) with 2 equiv of 2,6-disubstituted phenols bearing sterically bulky tert-butyl or phenyl groups. The strongly coordinating solvents THF, tetrahydrothiophene
Publikováno v:
Inorganic chemistry. 38(21)
Several eighteen- and sixteen-electron derivatives of tungsten(0), molybdenum(0), and chromium(0) carbonyl complexes, including [PPN](2)[Cr(CO)(3)(O,S-C(6)H(4))] (2c), [PPN](2)[W(CO)(3)(NH,S-C(6)H(4))] (5c), [PPN](2)[W(CO)(3)(O,S-C(6)H(4))] (6c), [PP