Study of the Electronic Structure of M2(CH2CMe3)6 (M = Mo, W) by Photoelectron Spectroscopy and Density Functional Theory

Autor: Monica de Simone, Marcello Coreno, Roberta Totani, Nicolas E. Capra, Louis Messerle, Jennifer C. Green, Alfred P. Sattelberger

Publikováno v: Organometallics 41 (2021): 29–40. doi:10.1021/acs.organomet.1c00586
info:cnr-pdr/source/autori:de Simone, Monica; Coreno, Marcello; Totani, Roberta; Capra, Nicolas E.; Messerle, Louis; Green, Jennifer C.; Sattelberger, Alfred P./titolo:Study of the Electronic Structure of M-2(CH2CMe3)(6) (M = Mo, W) by Photoelectron Spectroscopy and Density Functional Theory/doi:10.1021%2Facs.organomet.1c00586/rivista:Organometallics/anno:2021/pagina_da:29/pagina_a:40/intervallo_pagine:29–40/volume:41

The valence electronic structures of two dinuclear alkyl compounds containing sigma(2)pi(4) triple bonds between group 6 metals, viz., M-2(CH2CMe3)(6) (M = Mo, W), have been investigated using a combination of molecular orbital theory and variable ph

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::683a18713340f082e22a1b9467bbc237
https://doi.org/10.1021/acs.organomet.1c00586

Redox chemistry of nickelocene-based monomers and polymers

Autor: Rebekah L. N. Hailes, Jennifer C. Green, Paul Gamm, William E. Geiger, Kevin Lam, Rebecca A. Musgrave, Ian Manners, Andrew D. Russell, Hazel A. Sparkes

Publikováno v: Musgrave, R A, Russell, A D, Gamm, P R, Hailes, R L N, Lam, K, Sparkes, H A, Green, J C, Geiger, W E & Manners, I 2021, ' Redox Chemistry of Nickelocene-Based Monomers and Polymers ', Organometallics, vol. 40, no. 12, pp. 1945–1955 . https://doi.org/10.1021/acs.organomet.1c00247

The oxidation of [n]nickelocenophanes [Ni(η5-C5H4)2(CH2)3] (3), [Ni(η5-C5H4)2(SiMe2)2] (10), [Ni(η5-C5H4)2(SiMe2)2O] (11), [Ni(η5-C5H4)2(CH2)4] (12), and poly (nickelocenylpropylene) [Ni(η5-C5H4)2(CH2)3]n (4) to both the monocationic and dicatio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f4085560b555324f0291de4fe529a8a
http://gala.gre.ac.uk/id/eprint/33248/1/33248_LAM_Redox_chemistry_of_nickelocene_based_monomers_and_polymers.pdf

Bonding in pentalene complexes and their recent applications

Autor: Alexander F. R. Kilpatrick, Dermot O'Hare, F. Geoffrey N. Cloke, Jennifer C. Green

Publikováno v: Coordination Chemistry Reviews. 344:238-262

Molecular orbital (MO) theory is used to describe the bonding in transition metal pentalene complexes in a variety of its coordination modes. The various MO models account for structural parameters and lead to simple rules for electron counting in pe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::25797da3f7aea2df74d7aba065608689
https://doi.org/10.1016/j.ccr.2016.12.006

Periodic Trends Revealed by Photoelectron Studies of Transition Metal and Lanthanide Compounds

Autor: Jennifer C. Green

The application of photoelectron spectroscopy to metallocenes, tetrahedral molecules, metal dimers and clusters, and lanthanides and actinides, interpreted through molecular orbital theory, reveals periodic trends, which, in turn, help spectral assig

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::98f347a4f0f175431ba081f0ee7e71d6
https://doi.org/10.1007/430_2019_37

Abstract PO-018: Hematology oncology COllaborative VIDeoconferencing (COVID) Learning Initiative: A multi-institutional trainee alliance to rapidly disseminate emerging SARS-CoV2 and cancer best practices

Autor: Leo Reap, Charles Bodine, Samuel B Brusca, Richard L. Martin, Michael J. Grant, Jori May, Jennifer C. Green, Christine M. Lovly, Shonali Middha, Frances A. Collichio, David Furfaro, Jill Gilbert, Rushad Patell

Publikováno v: Clinical Cancer Research. 26:PO-018

Introduction: The SARS-CoV2 pandemic impacted numerous aspects of medical practice, including continuing medical education. In-person and single-institution educational formats could not address the challenges of social distancing, heterogeneous regi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ce4aa1ed17b9db8d9d72d89eb378fb2b
https://doi.org/10.1158/1557-3265.covid-19-po-018