Zobrazeno 1 - 10
of 21
pro vyhledávání: '"Jennifer A. Dabrowski"'
Publikováno v:
Journal of Chemical Education. 98:1610-1621
While scientists place high value on the scientific method, its relevance to everyday life is often opaque to nonscientists. In undergraduate teaching, its implementation is primarily apportioned to upper-level, laboratory science classes for majors.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::429cca52901fc25e562ebb2cf437f7c8
https://doi.org/10.1021/acs.jchemed.0c01446
https://doi.org/10.1021/acs.jchemed.0c01446
Publikováno v:
Journal of Chemical Education. 97:1283-1288
How do we engage students outside their major discipline? Recent curriculum changes have led to increases in nonlaboratory science course offerings for nonmajors to not only bolster science literac...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::263aa667ca72e7d3c5f64a9381aa4e9a
https://doi.org/10.1021/acs.jchemed.9b00964
https://doi.org/10.1021/acs.jchemed.9b00964
Publikováno v:
Nature Reviews Chemistry. 2:35-46
The transition from petroleum to biorenewable sources of carbon to meet our energy and chemical feedstock needs is difficult, in part because these sources are so different, with petroleum being under-functionalized and biomass being over-functionali
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::13ac145c008ec0cb876c95bf73aa9c4d
https://doi.org/10.1038/s41570-018-0005-y
https://doi.org/10.1038/s41570-018-0005-y
Publikováno v:
ACS Catalysis. 6:8399-8403
A set of B(C6F5)3-catalyzed methods for diversification of unsaturated carbohydrate derived substrates is disclosed. Lewis acid cyclization, allylic alcohol hydrosilylation, and selective silyl group exchange is achieved with this single versatile ca
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0c3fdcb35a5accb363931e8258ff2fee
https://doi.org/10.1021/acscatal.6b02551
https://doi.org/10.1021/acscatal.6b02551
Publikováno v:
ChemInform. 47
Selective carbocyclizations of unsaturated carbohydrates yield cyclopentanes and cyclopropanes via sila-THF cations as key intermediates.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::255c91d2986a26b49dfd3fc9ea0435c7
https://doi.org/10.1002/chin.201652059
https://doi.org/10.1002/chin.201652059
Publikováno v:
Angewandte Chemie. 125:7848-7853
All-catalytic route to trisubstituted allenes: The first examples of catalytic enantioselective allylic substitution reactions that involve alkyne-based nucleophiles and lead to products having tertiary stereogenic centers are followed by an exceptio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d6f097e46bd59849d8031833c42329cc
https://doi.org/10.1002/ange.201303501
https://doi.org/10.1002/ange.201303501
Publikováno v:
Angewandte Chemie. 125:8314-8317
Development of methods for efficient catalytic enantioselective conjugate addition (ECA) of readily accessible carbon-based nucleophiles to α,β-unsaturated carbonyls is a major objective of research in chemical synthesis.[1] Progress has been made
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::001dc214a91d4945ccb1ff2b78cc7b19
https://doi.org/10.1002/ange.201304035
https://doi.org/10.1002/ange.201304035
Publikováno v:
Organic letters. 18(16)
A B(C6F5)3-catalyzed method for the selective conversion of unsaturated carbohydrates to cyclopentanes and cyclopropanes is disclosed. Catalyst activation of tertiary silanes generates the ion pair [(C6F5)3B–H][ROSi2] whose components synergistical
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::07c27d4f43e00b179a84198d2c87f61b
https://pubmed.ncbi.nlm.nih.gov/27508492
https://pubmed.ncbi.nlm.nih.gov/27508492
Publikováno v:
Journal of the American Chemical Society. 133:4778-4781
A catalytic enantioselective method for the formation of alkyne-substituted all-carbon quaternary stereogenic centers is reported. Additions of alkynylaluminums to alkyl-, aryl-, carboxylic ester-, or silyl-substituted allylic phosphates are promoted
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::969ac8c154c3b421ee2d605215e25a9b
https://doi.org/10.1021/ja2010829
https://doi.org/10.1021/ja2010829
Publikováno v:
Journal of the American Chemical Society. 133:736-739
A catalytic method for enantioselective conjugate addition (ECA) of Si-containing vinylaluminum reagents to β-substituted cyclopentenones and cyclohexenones is described. Reactions are promoted by 1.0–5.0 mol % of a bidentate NHC–Cu complex, whi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc4947aebdee758a58995f2cf6d927e9
https://doi.org/10.1021/ja110054q
https://doi.org/10.1021/ja110054q