Zobrazeno 1 - 10
of 29
pro vyhledávání: '"Jenifer C. Braley"'
Autor:
Kevin McCann, Stephen G. Boyes, Bruce J. Mincher, Georges Saint-Louis, Laurence Berthon, Christopher A. Zarzana, Kristyn M. Roscioli-Johnson, Philippe Guilbaud, Julie M. Muller, Jenifer C. Braley, Stephen P. Mezyk, Gary S. Groenewold, Jessica A. Drader, Cathy Rae, M-C Charbonnel
Publikováno v:
Solvent Extraction and Ion Exchange. 35:480-495
The radiolytic degradation of di-2-ethylhexyl-isobutyramide (DEHiBA) was examined by subjecting the compound to gamma irradiation, measuring the remaining concentration of the intact compound, identifying the degradation products, and measuring urani
Publikováno v:
Separation & Purification Reviews. 47:49-65
Separations of used nuclear fuel at the engineered scale have generally been completed using the Plutonium Uranium Redox Extraction (PUREX) process. The PUREX process uses tributyl phosphate (TBP) as an extractant to recover uranium and plutonium. Wh
Publikováno v:
Physical Chemistry Chemical Physics. 19:11326-11339
Extraction of polar molecules by amphiphilic species results in a complex variety of clusters whose topologies and energetics control phase behavior and efficiency of liquid–liquid separations. A computational approach including quantum mechanical
Publikováno v:
The Journal of Physical Chemistry B. 120:12184-12192
Diffusion nuclear magnetic resonance (NMR) spectroscopy was used to find the interaggregate interactions and sizes of tributyl phosphate (TBP) aggregates containing varying concentrations of uranium or zirconium and HNO3 in an n-dodecane diluent. The
Publikováno v:
Inorganic Chemistry. 55:11971-11978
Separation of americium from the lanthanides is considered one of the most difficult separation steps in closing the nuclear fuel cycle. One approach to this separation could involve oxidizing americium to the hexavalent state to form a linear dioxo
Autor:
Jenifer C. Braley, Kevin McCann, Patrizia P. Smith, Stephen G. Boyes, Liping Zhu, Jessica A. Drader
Publikováno v:
Separation and Purification Technology. 163:352-356
The potential of monoamide-based extraction chromatographic materials for actinide recovery was assessed by monitoring uranium partitioning into six different materials. These materials were comprised of two solid supports (Amberlite XAD 4 and XAD 7)
Publikováno v:
The Journal of Physical Chemistry B. 120:2796-2806
A molecular dynamics model for tributyl phosphate (TBP) and diamyl amyl phosphonate (DAAP) is presented using the Generalized AMBER Force Field (GAFF) and the AM1-BCC method for calculated atomic charges with a modification to the phosphorus-containi
Publikováno v:
Solvent Extraction and Ion Exchange. 34:114-125
The complexation thermodynamics of trivalent actinides with (poly)aminopolycarboxylates (APCs) are reviewed to assess aspects of covalency and selectivity in actinide-amine interactions. The preferential interaction of APC ligands with trivalent acti
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 306:31-38
Using the Westcott convention, the Westcott flux, $$ \varphi_{\text{w}} $$ ; modified spectral index, $$ r\sqrt {T_{n} /T_{0} } $$ ; neutron temperature, T n; and gold-based cadmium ratios were determined for various sampling positions in the U.S. Ge
Publikováno v:
Solvent Extraction and Ion Exchange. 31:567-577
Combining octyl(phenyl)-N,N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) into a single process solvent for separating transuranic elements from liquid high-level waste is explored