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pro vyhledávání: '"Jeffrey S. Rommel"'
Publikováno v:
Inorganic Chemistry. 31:5022-5027
The ability of the aromatic diisocyanide ligand 1,4-diisocyanobenzene to act as a mediator for charge polarization between W(0) and W(II) centers was investigated. A series of bridged complexes were synthesized which contained (0)-W(0), W(0)-W(II), a
Publikováno v:
Inorganic Chemistry. 27:2945-2949
C 24 H 19 N 2 O 8 P 2 W 2 cristallise dans P2 1/n avec affinement jusqu'a 0,0399. C 52 H 34 N 2 O 8 P 2 W 2 cristallise dans P2 1/n avec affinement jusqu'a 0,0452
Publikováno v:
Inorganic Chemistry. 27:2942-2945
{sup 13}C, {sup 17}O, and {sup 14}N NMR spectra for the tungsten isocyanide complexes W(CO){sub 6-n}(CNR){sub n} (R = tert-butyl, p-tolyl; n = 1-3) have been obtained and the magnitudes of the corresponding chemical shifts utilized as a probe of diff