Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Jeffrey D, Sears"'
Publikováno v:
Angewandte Chemie. 134
Publikováno v:
Angew Chem Int Ed Engl
Herein, we expand the current molecular-level understanding of one of the most important and effective additives in iron-catalyzed cross-coupling reactions, N,N,N’,N’-tetramethylethylenediamine (TMEDA). Focusing on relevant phenyl and ethyl Grign
Autor:
Valerie E. Fleischauer, Daniel J. Curran, Peter G. N. Neate, Stephanie H. Carpenter, Michael L. Neidig, Joshua C. DeMuth, Jeffrey D. Sears, Theresa E. Iannuzzi, Nikki J. Wolford
Publikováno v:
Accounts of Chemical Research. 52:140-150
Since the pioneering work of Kochi in the 1970s, iron has attracted great interest for cross-coupling catalysis due to its low cost and toxicity as well as its potential for novel reactivity compared to analogous reactions with precious metals like p
Publikováno v:
Comprehensive Coordination Chemistry III ISBN: 9780081026892
Comprehensive Coordination Chemistry III
Comprehensive Coordination Chemistry III
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4f7c43c15cd6c3d68f1b4e0557c44030
https://doi.org/10.1016/b978-0-08-102688-5.00050-7
https://doi.org/10.1016/b978-0-08-102688-5.00050-7
Autor:
William W. Brennessel, Jeffrey D. Sears, Tessa M. Baker, Stephanie H. Carpenter, Stephanie L. Daifuku, Michael L. Neidig, Salvador B. Muñoz
Publikováno v:
Angewandte Chemie. 130:6606-6610
The use of N-methylpyrrolidone (NMP) as a co-solvent in ferric salt catalyzed cross-coupling reactions is crucial for achieving the highly selective, preparative scale formation of cross-coupled product in reactions utilizing alkyl Grignard reagents.
Autor:
Michael L. Neidig, Salvador B. Muñoz, Jeffrey D. Sears, Maria Camila Aguilera Cuenca, William W. Brennessel
Publikováno v:
Polyhedron. 158
Homoleptic iron-alkyl complexes have been implicated as key intermediates in iron-catalyzed cross-coupling with simple iron salts. Tetraalkyliron(III) ferrate species have been shown to be accessible with either methyl or benzyl ligands, where the fo
Autor:
Salvador B. Muñoz, Stephanie L. Daifuku, Ari A. Shaps, Jeffrey D. Sears, William W. Brennessel, Michael L. Neidig, Stephanie H. Carpenter
The elucidation of the effects of β-hydrogen containing alkyl Grignard reagents in simple ferric salt cross-coupling is presented. The reaction of FeCl(3) with EtMgBr in THF leads to the formation of the cluster species [Fe(8)Et(12)](2−), a rare e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5f7fd48a93639957aa19b5b7670c3d40
https://europepmc.org/articles/PMC6472485/
https://europepmc.org/articles/PMC6472485/
Autor:
Curtis E. Moore, Anthony M. Mrse, Myles J. Drance, Joshua S. Figueroa, Michael L. Neidig, Jeffrey D. Sears, Arnold L. Rheingold
Publikováno v:
Science (New York, N.Y.). 363(6432)
Iron's new Best Friend Carbon monoxide (CO) is one of the most widely studied ligands in the chemistry of transition metals. One of its distinguishing features is a two-way bonding motif, in which CO donates electrons to the metal while the metal sim
Publikováno v:
Non-Noble Metal Catalysis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4f6e8f9ff94c1f0fc456bb9a80744c27
https://doi.org/10.1002/9783527699087.ch11
https://doi.org/10.1002/9783527699087.ch11
Publikováno v:
Journal of the American Chemical Society. 138:11360-11367
We herein report a new catalytic method for intermolecular olefin aminofluorination using earth-abundant iron catalysts and nucleophilic fluoride ion. This method tolerates a broad range of unfunctionalized olefins, especially nonstyrenyl olefins tha