Zobrazeno 1 - 10
of 381
pro vyhledávání: '"Jeff W, Kampf"'
Publikováno v:
Inorganics, Vol 12, Iss 3, p 75 (2024)
Co bis(benzenedithiolate) type complexes have captivated chemists for decades for their interesting geometric and electronic structures and more recently, for their impressive ability to mediate the hydrogen evolution reaction (HER) both photo- and e
Externí odkaz:
https://doaj.org/article/d8548cdbad1143d6b8dacf618f6601c2
Publikováno v:
Journal of the American Chemical Society. 144:21030-21034
Autor:
Elvin V. Salerno, Albano N. Carneiro Neto, Svetlana V. Eliseeva, Miguel A. Hernández-Rodríguez, Jacob C. Lutter, Timothée Lathion, Jeff W. Kampf, Stéphane Petoud, Luis D. Carlos, Vincent L. Pecoraro
Publikováno v:
Journal of the American Chemical Society. 144:18259-18271
The effect of ligands' energy levels on thermal dependence of lanthanide emission was examined to create new molecular nanothermometers. A series of Ln2Ga8L8′L8″metallacrowns (shorthand Ln2L8′), where Ln = Gd3+, Tb3+, or Sm3+(H3L′ = salicylhy
Autor:
Corey J. White, Michael O. Lengel, Abigail J. Bracken, Jeff W. Kampf, Amy L. Speelman, E. Ercan Alp, Michael Y. Hu, Jiyong Zhao, Nicolai Lehnert
Publikováno v:
Journal of the American Chemical Society. 144:3804-3820
Autor:
Elvin V. Salerno, Collin M. Foley, Vittoria Marzaroli, Bernadette L. Schneider, Max D. Sharin, Jeff W. Kampf, Luciano Marchiò, Matthias Zeller, Régis Guillot, Talal Mallah, Matteo Tegoni, Vincent L. Pecoraro, Curtis M. Zaleski
Publikováno v:
European Journal of Inorganic Chemistry. 2022
Publikováno v:
Chemical Communications. 57:11705-11708
A series of iridium hydride complexes featuring dihydrogen bonding are presented and shown to undergo rapid H+/H− exchange (1240 s−1 at 25 °C). We demonstrate that the H+/H− exchange rate can be modified by post-synthetic modification at a rem
Publikováno v:
Inorganic Chemistry Frontiers. 8:2611-2623
Two GdIII FeIII4 metallacrown complexes are presented and analyzed for their magnetic properties. One of these species is newly identified and exhibits a bent ring geometry as opposed to the more conventional flatter conformation of the other. Both c
Publikováno v:
Journal of the American Chemical Society. 142:18698-18705
When subjected to arylboranes, anionic trifluoromethyl and difluorobenzyl palladium(II) complexes undergo fluoride abstraction followed by 1,1-migratory insertion. The resulting intermediate fluoroalkyl species can be induced to undergo a subsequent
Autor:
Stéphane Petoud, Tu N. Nguyen, Svetlana V. Eliseeva, Chun Y. Chow, Vincent L. Pecoraro, Jeff W. Kampf
Publikováno v:
Inorganic Chemistry Frontiers
Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2020, 7 (7), pp.1553-1563. ⟨10.1039/c9qi01647c⟩
Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2020, 7 (7), pp.1553-1563. ⟨10.1039/c9qi01647c⟩
International audience; A new series of gallium(iii)/lanthanide(iii) metallacrown (MC) complexes (Ln-1) was synthesized by the direct reaction of salicylhydroxamic acid (H(3)shi) with Ga-III and Ln(III) nitrates in a CH3OH/pyridine mixture. X-ray sin
Autor:
Svetlana V. Eliseeva, Tu N. Nguyen, Jeff W. Kampf, Evan R. Trivedi, Vincent L. Pecoraro, Stéphane Petoud
Publikováno v:
Chemical Science
Chemical Science, 2022, 13 (10), pp.2919-2931. ⟨10.1039/d1sc06769a⟩
Chemical Science, 2022, 13 (10), pp.2919-2931. ⟨10.1039/d1sc06769a⟩
International audience; A family of Zn16Ln(HA)16 metallacrowns (MCs; Ln = YbIII, ErIII, and NdIII; HA = picoline- (picHA2−), pyrazine- (pyzHA2−), and quinaldine- (quinHA2−) hydroximates) with an ‘encapsulated sandwich’ structure possesses o