Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Jean-Yves Calves"'
Publikováno v:
Inorganica Chimica Acta. 33:95-99
The exchanges occuring in the {NbOCl 3 (diket)} − ions are not observed when the “oxo” ligand is replaced by a peroxide ion. This is the third example of rigidity in heptacoordinated complexes containing the “peroxo” group. This behaviour i
Autor:
Jean-Yves Calves, J. E. Guerchais
Publikováno v:
Journal of Fluorine Chemistry. 4:47-56
Resume L'ion peroxotetrafluorotantalate(V), {Ta(O-O)F4(H2O)}- ainsi qu'une serie de peroxotrifluoro β-dicetonato tantalates(V) de formule generale {Ta(O-O)F3-(RCOCHCOR′)}- ont ete caracterises a l'etat solide par les methodes physiques habituelles
Autor:
J. Sala-Pala, Anthony J. Edwards, J. C. Dewan, Jean-Yves Calves, Jacques E. Guerchais, S. Brownstein
Publikováno v:
Canadian Journal of Chemistry. 56:1545-1548
Hydrolysis of (Et4N)[TaF6] with Et4NOH in organic medium gives (Et4N)2[Ta2OF10]. The Ta—O—Ta infrared and Raman frequencies reflect the linearity of the bridge, in agreement with a previous X-ray study. The 19F nmr spectrum is of the type AA′E4
Autor:
Jean-Yves Calves, J. E. Guerchais
Publikováno v:
Journal of the Less Common Metals. 32:155-163
Resume Les produits M{Nb(O-O)F4(H2O)}, M{Nb(O-O)F3(RCOCHCOR′)} et M2{Nb2(O-O)2F6(C2O4)} avec M = N(C2H5)4 ont ete isoles. Les quatre fluors semblent equivalents pour l'ion peroxotetrafluore en solution dans le methanol. Aux anions monomeres {Nb(O-O
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 37:1294-1296
Publikováno v:
Chemischer Informationsdienst. 6
Publikováno v:
Chemischer Informationsdienst. 8
Autor:
Ronald J. Gillespie, Jean-Yves Calves
Publikováno v:
Chemischer Informationsdienst. 7
It is shown by 19F and 1H n.m.r. spectroscopy that the complex MeF–SbF5 does not exist in solution in SO2, as the solvent is methylated with the formation of CH3OSO+, but it can be obtained in SO2F2 as a stable species which undergoes neither intra
Publikováno v:
Chemischer Informationsdienst. 6
Publikováno v:
Chemischer Informationsdienst. 8