Zobrazeno 1 - 10
of 46
pro vyhledávání: '"Jean-Pierre Sawerysyn"'
Autor:
Nicolas Visez, Jean-Pierre Sawerysyn
Publikováno v:
Chemosphere. 73:S90-S93
Chlorination and thermal degradation of 2-chlorodibenzodioxin and dibenzofuran were investigated using sealed tubes at 350 °C in the presence of CuCl 2 or CuCl. Twelve organic species, including polychlorobenzenes, were identified and quantified as
Autor:
Nicolas Visez, Jean-Pierre Sawerysyn
Publikováno v:
Chemosphere. 67:S144-S149
The oxidative degradation of 2-chlorophenol in air (equivalence ratio ϕ = 0.8) was investigated at 350 °C by using the sealed tube technique under different conditions: in the gas phase and in the presence of copper chlorides (CuCl2 and CuCl in dif
Publikováno v:
Chemosphere. 62:1806-1816
The thermal oxidation of 2-chlorophenol (2-CP) in air was investigated using a perfectly stirred reactor at 1 atm over the temperature range 450-900 degrees C. The relative concentration of 2-CP was 1,000 ppm V (equivalence ratio Phi=0.03). About fif
Publikováno v:
International Journal of Chemical Kinetics. 32:548-565
Thermodynamic properties (ΔH°f(298), S°(298) and Cp(T) from 300 to 1500 K) for reactants, adducts, transition states, and products in reactions of CH3 and C2H5 with Cl2 are calculated using CBSQ//MP2/6-311G(d,p). Molecular structures and vibration
Publikováno v:
Chemosphere. 38:2835-2848
The thermal degradation processes of chlorobenzene were investigated using a tubular flow reactor at I atm. over the range 575–825°C in reaction atmospheres in which oxygen was in excess (equivalence ratio Φ = 0.035). The concentration profiles o
Publikováno v:
Chemical Physics Letters. 254:203-212
The rate constants for the reactions CF 3 O 2 + NO → CF 3 O + NO 2 (1) and CF 3 O + NO → products (2) have been measured at room temperature using a fast flow reactor associated with a monitoring of CF 3 O radicals by laser induced fluorescence (
Publikováno v:
Chemosphere. 32:1261-1273
Thermal degradation processes of 1,3-hexachlorobutadiene (C4Cl6) have been studied using a tubular flow reactor at 1 atm over the temperature range 500–1100°C for residence times of 2 seconds. Kinetic studies were performed with mixtures of 1000 p
Publikováno v:
The Journal of Physical Chemistry. 99:15102-15107
The rates of the atmospherically important reactions of the CF{sub 3}O radical with methane (k{sub 6}), ethane (k{sub 7}), and isobutane (k{sub 8} ) have been measured at low pressure (nearly equal to 1 Torr) with the fast flow tube technique associa
Publikováno v:
The Journal of Physical Chemistry. 98:11342-11352
Publikováno v:
International Journal of Chemical Kinetics. 25:399-413
The kinetics of the reaction of the benzyl radical with molecular oxygen has been studied between 393 and 433 K. The Discharge Flow technique with detection of benzyl radicals by Laser Induced Fluorescence in their visible absorption band has been us