Unusual oxidative stability of a multidentate primary amine ligand: facile synthesis of the oxo-bridged diiron(III) complex

Autor: Gadde Ramachandraiah, Olivier Horner, Jesús Pitarch López, Frank W. Heinemann, Andreas Grohmann, Jean-Mare Latour

Publikováno v: Inorganic Chemistry Communications
Inorganic Chemistry Communications, Elsevier, 2004, 7, pp.773-776. ⟨10.1016/j.inoche.2004.03.026⟩
Inorganic Chemistry Communications, 2004, 7, pp.773-776. ⟨10.1016/j.inoche.2004.03.026⟩

International audience; The tetrapodal pentaamine 2,6-C5H3N[CMe(CH2NH2)2]2 (pyN4, 1), which possesses four equivalent primary amino groups, has been used to prepare the diiron(III) oxo complex [(1)2Fe2(μ2-O)](ClO4)4(2), by aerobic oxidation of the m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::756e7d4632a6c39a9f1797c926b84f1e
https://doi.org/10.1016/j.inoche.2004.03.026