Clear-cut difference in the rearrangement of 1-bromo-2-(2-phenyl-3-butenyl)benzene under anionic or radical conditions

Autor: Céline Reynaud, Hassan Hazimeh, Jean-Marc Mattalia, Caroline Marchi-Delapierre, Michel Chanon

Publikováno v: ARKIVOC, Vol 2011, Iss 10, Pp 33-43 (2011)

Externí odkaz: https://doaj.org/article/a3a702dabe0a4920bc37ae7808df8684

When a very fast radical probe cyclization hints at a carbanionic intermediate rather than at a radical one: a further proof of a polar mechanism for the aryl bromide–alkyllithium exchange reaction

Autor: Nicolas Bodineau, Norma S. Nudelman, Graciela V. García, Jean-Marc Mattalia, Rogério Martins, Michel Arbelot, Michel Chanon

Publikováno v: ARKIVOC, Vol 2002, Iss 5, Pp 139-150 (2002)

Externí odkaz: https://doaj.org/article/2154a41b024442a188de66fdc613a129

The reductive decyanation reaction: an overview and recent developments

Autor: Jean-Marc Mattalia

Publikováno v: Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 267-284 (2017)
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2017, 13, pp.267-284. ⟨10.3762/bjoc.13.30⟩
Beilstein Journal of Organic Chemistry, 2017, 13, pp.267-284. ⟨10.3762/bjoc.13.30⟩

International audience; This review presents an overview of the reductive decyanation reaction with a special interest for recent developments. This transformation allows synthetic chemists to take advantages of the nitrile functional group before it

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3fe94a4fa051d420d06109d68130b1e8
https://doaj.org/article/0ab1b18f4db74d1a85223b3e3ae8b155

Gold-catalyzed cycloisomerizations of 1,6-enynes. A computational study

Autor: Jean-Marc Mattalia, Paola Nava

Publikováno v: Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, 2014, 749, pp.335-342. ⟨10.1016/j.jorganchem.2013.09.041⟩
Journal of Organometallic Chemistry, Elsevier, 2014, 749, pp.335-342. ⟨10.1016/j.jorganchem.2013.09.041⟩

The catalytic activity of gold phosphines for enyne cycloisomerizations is related to the very special bonding between the metal center and its substrate. We have computed mechanistic energy profiles for the formation of key 5- or 6-membered ring int

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b8474c375ba167c0521f5fcd0c6e142
https://doi.org/10.1016/j.jorganchem.2013.09.041

About the Inhibition of Grignard Reagent Formation byp-Dinitrobenzene: Comparing the Mechanism of Grignard Reagent Formation and the SRN1 Mechanism

Autor: Jean-Claude Négrel, Nicolas Bodineau, Vitaliy I. Timokhin, Jean-Marc Mattalia, Kishan Handoo, Hassan Hazimeh, Michel Chanon

Publikováno v: European Journal of Organic Chemistry. 2010:2476-2486

Both S RN 1-type reactions and Grignard reagent formation are inhibited by trace amounts (with respect to the halide) of p-dinitrobenzene (DNB) and other oxidising agents such as CuCl 2 or dioxygen. Both are believed to be triggered by an electron-tr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cdb06ac15cc5167ddcd75053d554dd76
https://doi.org/10.1002/ejoc.200901469