Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Jean-Claude Bünzli"'
Autor:
Xiao-Zhen Li, Li-Peng Zhou, Liang-Liang Yan, Ya-Min Dong, Zhuan-Ling Bai, Xiao-Qi Sun, Juan Diwu, Shuao Wang, Jean-Claude Bünzli, Qing-Fu Sun
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
Lanthanide ions possess similar chemical properties, making their separation from one another challenging. Here the authors show that a tris-tridentate ligand causes high-precision metal ion self-sorting, leading to the selective assembly of tetrahed
Externí odkaz:
https://doaj.org/article/9d86e352937445469eec0ba488696d54
Autor:
Zicheng Li, Bolong Zhang, Zhihao Zhang, Jean-Claude Bünzli, Abd. Rashid bin Mohd Yusoff, Yong-Young Noh, Peng Gao
Publikováno v:
Materials Science and Engineering: R: Reports. 152:100710
Metal-halide perovskites-based optoelectronic devices, such as solar cells and light-emitting diodes (LEDs), are transitioning from promising performers to direct competitors to well-established technologies due to the advantage of cost-effectiveness
Autor:
Jean-Claude Bünzli
Publikováno v:
Helvetica Chimica Acta. 88:375-379
Publikováno v:
Modern Aspects of Rare Earths and Their Complexes
This chapter discusses the effects of paramagnetism on nuclear magnetic resonances (NMR) of the ligand molecules by using lanthanide induced shift (LIS). Many lanthanide shift reagents are now available commercially, which are soluble in common organ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::03be66b713d255ca60f7f9f2531c8501
https://doi.org/10.1016/b978-044451010-5/50024-9
https://doi.org/10.1016/b978-044451010-5/50024-9
This chapter discusses organometallic complexes of rare earths. The 4f orbitals in the lanthanides are well shielded and the metals do not experience an effective nuclear charge as the 5p, 6s, or 5d orbitals. In spite of this, the 4f orbitals become
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::898e3d6f700aafac6e56b74147916ba4
https://doi.org/10.1016/b978-044451010-5/50020-1
https://doi.org/10.1016/b978-044451010-5/50020-1
The lanthanide series of elements differ from the transition metal series in that 4f shell inner electrons are shielded by the 5s 2 , 5p 6 closed shells. Consequently f shell electrons interact much less strongly with their environment than the d ele
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cd8283d11606f5967eb6618497862440
https://doi.org/10.1016/b978-044451010-5/50022-5
https://doi.org/10.1016/b978-044451010-5/50022-5
This chapter discusses the structural chemistry of lanthanide complexes including their complex formation and coordination number. These factors for rare earth ions are different from those of transition metals. The chemical composition of rare earth
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::82a8bb4189ec7206766e89aff278af01
https://doi.org/10.1016/b978-044451010-5/50019-5
https://doi.org/10.1016/b978-044451010-5/50019-5
This chapter deals with quantum mechanics. It uses Schrodinger equation to describe energy levels and other properties of electrons in atoms and molecules. The Schrodinger equation is a second order differential equation and the solutions, ψ ( x , y
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::02d02ad48cbb910fc4c11bcb4b6b4d36
https://doi.org/10.1016/b978-044451010-5/50016-x
https://doi.org/10.1016/b978-044451010-5/50016-x
This chapter discusses different applications of rare earths such as deoxidizers and desulphurizers in steels. Addition of rare earths to steels improves physical, mechanical, and chemical properties of steels. Rare earth metal salts are effective in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7dff7e7d1196c75160397784bdcab996
https://doi.org/10.1016/b978-044451010-5/50026-2
https://doi.org/10.1016/b978-044451010-5/50026-2