Catalytic Nitrene Transfer by an Fe IV ‐Imido Complex Generated by a Comproportionation Process

Autor: Jordan Donat, Patrick Dubourdeaux, Martin Clémancey, Julia Rendon, Clara Gervasoni, Morgan Barbier, Jessica Barilone, Jacques Pécaut, Serge Gambarelli, Pascale Maldivi, Jean‐Marc Latour

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, In press, ⟨10.1002/chem.202201875⟩

International audience; Nitrene transfer reactions have emerged as one of the most powerful and versatile ways to insert an amine function to various kinds of hydrocarbon substrates. However, the mechanisms of nitrene generation have not been studied

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b11d9cb0d525832a66d04cc12440ee0
https://doi.org/10.1002/chem.202201875

Nitrene transfers mediated by natural and artificial iron enzymes

Autor: Guillaume Coin, Jean-Marc Latour

Publikováno v: Journal of Inorganic Biochemistry
Journal of Inorganic Biochemistry, Elsevier, 2021, 225, pp.111613. ⟨10.1016/j.jinorgbio.2021.111613⟩
Journal of Inorganic Biochemistry, 2021, 225, pp.111613. ⟨10.1016/j.jinorgbio.2021.111613⟩

International audience; Amines are ubiquitous in biology and pharmacy. As a consequence, introducing N functionalities in organic molecules is attracting strong continuous interest. The past decade has witnessed the emergence of very efficient and se

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c2eb2e6abd000901495c699f06133a1
https://hal.archives-ouvertes.fr/hal-03411941

Escherichia coli RIC is able to donate iron to iron-sulfur clusters.

Autor: Lígia S Nobre, Ricardo Garcia-Serres, Smilja Todorovic, Peter Hildebrandt, Miguel Teixeira, Jean-Marc Latour, Lígia M Saraiva

Publikováno v: PLoS ONE, Vol 9, Iss 4, p e95222 (2014)

Escherichia coli RIC (Repair of Iron Centers) is a diiron protein previously reported to be involved in the repair of iron-sulfur proteins damaged by oxidative or nitrosative stresses, and proposed to act as an iron donor. This possible role of RIC w

Externí odkaz: https://doaj.org/article/ce12fec42fad4ff49d2ec0a8e7a75c20

Spin State Tunes Oxygen Atom Transfer towards Fe IV O Formation in Fe II Complexes

Autor: Jean-Marc Latour, Laia Vicens, Ilaria Gamba, Carmen E. Castillo, Miquel Costas, Manuel G. Basallote, Martin Clémancey

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, 27 (15), pp.4946-4954. ⟨10.1002/chem.202004921⟩
Chemistry-A European Journal, 2021, 27 (15), pp.4946-4954. ⟨10.1002/chem.202004921⟩

International audience; Oxoiron(IV) complexes bearing tetradentate ligands have been extensively studied as models for the active oxidants in non-heme iron-dependent enzymes. These species are commonly generated by oxidation of their ferrous precurso

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::641c02d9cade65b4db73d2938a116149
https://hal.archives-ouvertes.fr/hal-03169725

Bioinspired symmetrical and unsymmetrical diiron complexes for selective oxidation catalysis with hydrogen peroxide

Autor: Geneviève Blondin, Martin Clémancey, Jean-Pierre Mahy, Régis Guillot, Frédéric Avenier, Jean-Marc Latour, Alexandre Trehoux

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2020, 49 (46), pp.16657-16661. ⟨10.1039/d0dt03308a⟩
Dalton Transactions, 2020, 49 (46), pp.16657-16661. ⟨10.1039/d0dt03308a⟩

International audience; Two new symmetrical and unsymmetrical diiron(iii) complexes were synthesized and characterized by X-ray diffraction analysis, mass spectrometry, UV-visible and Mossbauer spectroscopies. They proved to be good catalysts for alk

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::be642db4a862b86874e41f8399404c24
https://pubmed.ncbi.nlm.nih.gov/33196734