Zobrazeno 1 - 10
of 78
pro vyhledávání: '"Jean Grandjean"'
Publikováno v:
Clay Minerals. 43:205-212
Synthetic hectorites and the corresponding surfactant-exchanged clays have been characterized by X-ray diffraction and 1H, 7Li, 13C, 23Na and 29Si solid-state nuclear magnetic resonance (NMR) spectroscopy. The low-charge clays retain water more effic
Autor:
Bénédicte Vertruyen, Laurent Lepot, Rudi Cloots, Jean Grandjean, Natasha Krins, Bernard Gilbert, André Rulmont
Publikováno v:
Solid State Ionics. 177:3147-3150
Glassy materials are promising intercalation compounds, due to their open network structure and absence of grain boundaries. Some glasses containing alkali ions and a high concentration of transition metal ions can present mixed ionic-electronic cond
Autor:
Jean Grandjean
Publikováno v:
Clay Minerals. 41:567-586
Intercalation of surfactant and polymer chains between the clay platelets gives rise to molecular ordering that changes both the chain conformation and mobility with respect to the bulk phase. As a local probe, nuclear magnetic resonance is particula
Publikováno v:
Langmuir. 22:4818-4824
Modified laponites and synthetic saponites are used as precursors for the preparation of poly(epsilon-caprolactone) (PCL)/clay nanocomposites. The structure and dynamics of species intercalated in the modified clays and the corresponding nanocomposit
Publikováno v:
Langmuir. 20:9828-9833
The structure and dynamics of surfactant and polymer chains in intercalated poly(epsilon-caprolactone)/clay nanocomposites are characterized by (31)P magic-angle spinning (MAS) and (13)C cross-polarization MAS NMR techniques. To obtain hybrid materia
Autor:
Pattrick Vangeyte, Robert Jérôme, M. Heinrich, Claudie Bourgaux, Jean Grandjean, Bernard Leyh
Publikováno v:
Langmuir 20, 8442-8451 (2004). doi:10.1021/la049695y
The associative behavior of monodisperse diblock copolymers consisting of a hydrophilic poly(ethylene oxide) block and a hydrophobic poly(epsilon-caprolactone) or poly(gamma-methyl-epsilon-caprolactone) block has been studied in aqueous solution. Cop
Publikováno v:
Langmuir. 20:2982-2985
Publikováno v:
Clay Minerals. 38:367-373
13C CP MAS NMR and 29Si MAS NMR were used to characterize silylated montmorillonites and to estimate the extent of the silylation reaction. Indirectly-detected proton relaxation times of the intercalated surfactant were measured in both silylated and
Publikováno v:
Colloids and Surfaces B: Biointerfaces. 28:239-249
Proton NMR spectra for Cladonia mitis , hydrated to Δ m / m 0 =0.193, 0.126 and to 0.076, were recorded at different temperatures between room temperature and −45 °C. The loosely bound and free water fractions were selected for the observation us
Publikováno v:
Langmuir. 18:6159-6163
The structure and dynamics of surfactant molecules intercalated in Laponite have been characterized by solid-state 13C NMR relaxation times and 13C- and 29Si-detected proton relaxation times. These results are compared to similar data obtained for a