Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Jean Alex. Laffitte"'
Publikováno v:
Journal of Molecular Catalysis A: Chemical. :137-141
The Fries rearrangement of phenyl acetate for the paracetamol process is usually performed in hydrofluoric acid (HF). We have optimized this reaction with methane sulfonic acid (MSA), a strong, stable and biodegradable acid, to give para-hydroxyaceto
Publikováno v:
Scientific Reports
The effects of replacing the phenyl rings of triphenylamine (TPA) by naphtyl groups are analysed on a series of push-pull molecules containing a 2-thienyl-dicyanovinyl acceptor group. UV-Vis absorption spectroscopy and cyclic voltammetry show that th
Autor:
Jean Pierre Genêt, X. Pfister, Catherine Pinel, Virginie Ratovelomanana-Vidal, Jean-Alex Laffitte
Publikováno v:
Tetrahedron Letters. 35:4559-4562
The reduction of racemic β-keto esters having the tetralone structure by chiral ruthenium(II) catalysts is realized with an ideal kinetic dynamic resolution. Remarkably, high anti selectivity approaching 100% and enantioselectivity (up to 97%) using
Publikováno v:
Tetrahedron Letters. 35:3091-3094
The reduction of unsubstituted or methoxy-substituted (±)-2-carboxyethyl-1-tetralones by selected microorganisms affords optically active 1-hydroxy-2-carboxyethyl tetralins which can be used as versatile asymmetric synthons, for example in the prepa
Autor:
Jean Pierre Genêt, M.C.Caño De Andrade, Sergio Mallart, Virginie Ratovelomanana-Vidal, Catherine Pinel, X. Pfister, Jean-Alex Laffitte
Publikováno v:
Tetrahedron: Asymmetry. 5:665-674
A general and new synthesis of hexacoordinate chiral 1-[2-methylallyl]Ru II 2 complexes is presented. This synthesis uses the very accessible CODRu(2-methylallyl) 2 complex as starting material. These complexes (P*P)Ru(η 3 -(CH 2 ) 2 CCH 3 ) 2 (e.g.
Publikováno v:
ChemInform. 25
The reduction of unsubstituted or methoxy-substituted (±)-2-carboxyethyl-1-tetralones by selected microorganisms affords optically active 1-hydroxy-2-carboxyethyl tetralins which can be used as versatile asymmetric synthons, for example in the prepa
Autor:
Jean-Pierre Genêt, Catherine Pinel, Sergio Mallart, Jean Alex Laffitte, Sylvain Juge, Nathalie Cailhol
Publikováno v:
Tetrahedron Letters. 33:5343-5346
The synthesis of (R, R)DIPAMP ruthenium bis (2-methylallyl)2 and halogeno derivative (R, R) DIPAMPRu2X23 complexes is presented, which uses the easily available from (COD)2Ru(2-methylallyl)21. These new catalysts were found to be effective for asymme
Publikováno v:
Tetrahedron Letters. 31:6357-6360
The oxazaphopholidine borano complex 3 , prepared in one step from ephedrine, reacts with alkyl and aryl lithium compounds to afford regio and stereoselectively the corresponding aminophosphine complexes 4 . Acid methanolysis of 4 leads to the phosph
Publikováno v:
Journal of neurochemistry. 61(3)
(+)-S-Adenosyl-l-methionine [(+)-SAM] was isolated from rat brain and was quantified by HPLC followed by UV spectrophotometric measurements and by 1H-NMR. Its estimated ratio in brain is 3% of total SAM. Because of its commercial unavailability, (+)-
Publikováno v:
The Journal of Organic Chemistry. 51:3428-3435
Synthese de mercapto-3 cyclobutanol (A) a partir de chloromethyl oxiranne et du derive lithie du bis-trimethylsilylmethylthio-2 perhydro pyranne. L'heterocycle du titre substitue allyl-3 et le (Z)-methyl-3 dithiabicyclo [5.1.1] nonene-6 sont prepares