Characteristic vibrational frequencies of osmium(ii) nitrosyl complexes probed by Raman spectroscopy and DFT calculations

Autor: Nicolas Bélanger-Desmarais, Anatolie Gavriluta, Jean Bernard Tommasino, Christian Reber, Dominique Luneau

Publikováno v: New Journal of Chemistry. 46:9695-9703

Raman spectroscopy at variable temperature provides experimental frequencies for osmium(ii) nitrosyl complexes. Vibrational transitions are assigned using DFT calculations.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6e36142515af8d2678c24cd89167af62
https://doi.org/10.1039/d2nj01713j

Supramolecular assemblies of phenolic metalloporphyrins: Structures and electrochemical studies

Autor: Gia Co Quan, Morgane Denis, Brian Abeykoon, Jean-Bernard Tommasino, Erwann Jeanneau, Catherine Journet, Thomas Devic, Alexandra Fateeva

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e7d4b7c786d70e6cc5a715a8681ad8db
https://doi.org/10.1142/9789811223556_0073

Mononuclear manganese( iii ) complexes with reduced imino nitroxide radicals by single-electron transfer and intermolecular hydrogen bonds as an intramolecular structural driving force

Autor: Constance Lecourt, Cédric Desroches, Vivian Ferreol, Lhoussain Khrouz, Christian Reber, Jean-Bernard Tommasino, Nicolas Bélanger-Desmarais, Warren Madanamoothoo, Dominique Luneau

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2019, 48 (35), pp.13378-13387. ⟨10.1039/c9dt02158b⟩
Dalton Transactions, 2019, 48 (35), pp.13378-13387. ⟨10.1039/c9dt02158b⟩

International audience; Manganese(III) complexes were synthesized by one-electron transfer from a Mn(II) ion to the imino nitroxide radical 2-(2-imidazolyl)-4,4,5,5-tetramethylimidazoline-1-oxyl (IMImH) in methanol. After the manganese ions attained

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9925a85135e9585db3f1e25a5a28e693
https://hal.archives-ouvertes.fr/hal-02619047

Osmium–Nitrosyl Oxalato‐Bridged Lanthanide‐Centered Pentanuclear Complexes – Synthesis, Crystal Structures and Magnetic Properties

Autor: Ghenadie Novitchi, Jean Bernard Tommasino, Paul-Steffen Kuhn, Nicolas Claiser, Dominique Luneau, Anatolie Gavriluta, Olga Iasco, Vadim Druta, Vladimir B. Arion

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, 2015, 2015 (9), pp.1616-1624. ⟨10.1002/ejic.201500023⟩
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, 2015 (9), pp.1616-1624
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, 2015 (9), pp.1616-1624. ⟨10.1002/ejic.201500023⟩
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.1616-1624. ⟨10.1002/ejic.201500023⟩

International audience; A series of pentanuclear heterometallic coordination compounds of the general formula (Bu4N)(5)[Ln\Os(NO)(mu-ox)-Cl-3\(4)(H2O)(n)] [Ln = Y (for 2) and Dy (for 3') when n = 0; Ln = Dy (for 3), Tb (for 4), and Gd (for 5) when n

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aff74acd10b9a9f2b3c0837ec76b032a
https://doi.org/10.1002/ejic.201500023

Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

Autor: Alexandra Fateeva, Aude Demessence, Thomas Devic, M. Lions, Nathalie Guillou, Frédéric Maillard, Brian Abeykoon, Raphaël Chattot, Luis Cardenas, Jean-Bernard Tommasino

Publikováno v: Chemical Communications
Chemical Communications, Royal Society of Chemistry, 2017, 53 (48), pp.6496-6499. ⟨10.1039/c7cc02113e⟩

XPS+CDFA+ADM:LCS; International audience; Metal Organic Frameworks (MOFs) have been recently proposed as promising electrocatalysts, yet the exact nature of the mechanisms in play has not been addressed in depth. By comparing the electrocatalytic act

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::29e5bdd63b12d334ce8bba1cc5cac4de
https://hal.archives-ouvertes.fr/hal-01580221