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pro vyhledávání: '"Jea-Uk Chung"'
Publikováno v:
ChemInform. 25
Publikováno v:
ChemInform. 25
Reaction of chiral dienylic cyclic carbonates with dialkylcopper-magnesium complex R2CuMgX (RMgX: CuI=2: 1)BF3·OEt2 in THF at −78 °C for 30 min afforded γ-alkylated (E)-allylic alcohols with excellent regioselectivity and diastereoselectivity.
Publikováno v:
ChemInform. 26
Publikováno v:
The Journal of Organic Chemistry. 60:4678-4679
Publikováno v:
Tetrahedron: Asymmetry. 5:21-22
Reaction of chiral dienylic cyclic carbonates with dialkylcopper-magnesium complex R2CuMgX (RMgX: CuI=2: 1)BF3·OEt2 in THF at −78 °C for 30 min afforded γ-alkylated (E)-allylic alcohols with excellent regioselectivity and diastereoselectivity.
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :237
The decarboxylation–hydrogenolysis of prop-2-ynylic cyclic carbonates which have an internal acetylenic bond with ammonium formate in the presence of a catalytic amount of [Pd(acac)2] and Bun3P afforded (Z)-homoallylic alcohols or homoprop-2-ynylic