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Publikováno v:
Inorganic Chemistry. 59:15228-15239
Redox noninnocent ligands are known to be involved in altering the overall electronic nature of organometallic complexes by serving as an electron reservoir. Pyrazine(diimine) backbones in these complexes introduce enhanced π acidity over their more
The synthesis, molecular and electronic structures, and redox properties of pyrazine(diimine) (PzDI) metal dihalide complexes (DiPPPZDI)MX2 (DiPP = 2,6-diisopropylphenyl; M = Mn, Fe, Co, Ni; X = Cl, Br) are presented and compared. The dihalide comple
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