Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Jay J, Dunsford"'
Autor:
Michael W. Fay, James Adams, Athanasios Angelis-Dimakis, Jason E. Camp, Jay J. Dunsford, Joshua Britton, Thomas W. Bousfield
Publikováno v:
Synthesis. 50:3862-3874
A dehydrative cross-coupling of 1-phenylethanol catalysed by sugar derived, in situ formed palladium(0) nanoparticles under acidic conditions is realised. The acidic conditions allow for use of alcohols as a feedstock in metal-mediated coupling react
Autor:
Michael J. Ingleson, Rachel J. Kahan, S. Endres, Iñigo J. Vitorica-Yrezabal, J. E. Jones, Andrew J. Warner, Jay J. Dunsford, Daniel L. Crossley, Jessica Cid, R. A. Smith
Publikováno v:
Chemical Science
Ingleson, M, Kahan, R, Endres, S, Warner, A, Smith, R, Cid, J, Dunsford, J, Jones, J & Vitorica-Yrezabal, I 2017, ' A Modular Route to Boron Doped PAHs by Combining Borylative Cyclisation and Electrophilic C-H Borylation. ', Chemical Science . https://doi.org/10.1039/C7SC02793A
Ingleson, M, Kahan, R, Endres, S, Warner, A, Smith, R, Cid, J, Dunsford, J, Jones, J & Vitorica-Yrezabal, I 2017, ' A Modular Route to Boron Doped PAHs by Combining Borylative Cyclisation and Electrophilic C-H Borylation. ', Chemical Science . https://doi.org/10.1039/C7SC02793A
Starting from simple alkynes, sequential borylative cyclisation/electrophilic C–H borylation represents a simple modular route to novel B-doped PAHs.
Heteroatom doping into polyaromatic hydrocarbons (PAHs) is a powerful approach for modifying
Heteroatom doping into polyaromatic hydrocarbons (PAHs) is a powerful approach for modifying
Autor:
Oliver S. G. Dacosta, Robert D.J. Smith, Joshua Britton, Rebecca K. Blundell, Thomas W. Bousfield, Jason E. Camp, James Adams, Michael W. Fay, Jay J. Dunsford
Publikováno v:
RSC Advances. 6:16115-16121
In situ-generated, glucose-derived palladium(0) nanoparticles were shown to be convenient and effective catalysts for aqueous Mizoroki–Heck, Sonogashira and Suzuki–Miyaura cross-coupling reactions. The addition of only 4–10 mol% glucose to the
Autor:
Daniel L, Crossley, Pakapol, Kulapichitr, James E, Radcliffe, Jay J, Dunsford, Inigo, Vitorica-Yrezabal, Rachel J, Kahan, Adam W, Woodward, Michael L, Turner, Joseph J W, McDouall, Michael J, Ingleson
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Benzothiadiazole (BT) directed C−H borylation using BCl3, followed by B−Cl hydrolysis and Suzuki–Miyaura cross‐coupling enables facile access to twisted donor–acceptor compounds. A subsequent second C−H borylation step provides, on arylat
Publikováno v:
Dunsford, J J, Clark, E R & Ingleson, M J 2015, ' Direct C(sp(2))-C(sp(3)) Cross-Coupling of Diaryl Zinc Reagents with Benzylic, Primary, Secondary, and Tertiary Alkyl Halides ', ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 54, no. 19, pp. 5688-5692 . https://doi.org/10.1002/anie.201411403
The direct C(sp2)-C(sp3) cross-coupling of diaryl zinc reagents with benzylic, primary, secondary, and tertiary alkyl halides proceeded in the absence of coordinating ethereal solvents at ambient temperature without the addition of a catalyst. The C(
Autor:
Catrin Ffion Williams, Simon J. A. Pope, Simon J. Coles, Anthony Joseph Hayes, David Lloyd, Oliver J. Stacey, Jay J. Dunsford, Angelo James Amoroso, Peter N. Horton, James Alexis Platts
Publikováno v:
ResearcherID
A heterometallic, water soluble PtII–GdIII complex possesses visible luminescence and enhanced water relaxivity whilst showing promise and application in cell imaging studies.
Ring-Expanded N-Heterocyclic Carbenes for Copper-Mediated Azide-Alkyne Click Cycloaddition Reactions
Autor:
Filip, Sebest, Jay J, Dunsford, Matthew, Adams, Jeremy, Pivot, Paul D, Newman, Silvia, Díez-González
Publikováno v:
Chemcatchem
A series of well‐defined copper(I) complexes bearing ring‐expanded N‐heterocyclic carbene (NHC) ligands has been applied to the azide–alkyne cycloaddition reaction. The obtained results notably showed that the six‐membered NHC ligands outpe
Publikováno v:
Organometallics
The relative (to BEt3) hydride ion affinity (HIA) of a series of acridine borenium salts has been calculated, with some HIAs found to be similar to that for [Ph3C]+. The HIA at the acridine C9 position is controlled by both acridine and the boron sub
Autor:
Jay J. Dunsford, Kingsley J. Cavell
Publikováno v:
Organometallics. 33:2902-2905
The synthesis and characterization of the new six- and seven-membered Pd–PEPPSI-type N-heterocyclic carbene (NHC) complexes 3 and 4 is described. Complexes of the general formula [Pd(NHC)(3ClPy)Cl2] (NHC = 6- or 7-Mes, 3ClPy = 3-chloropyridine) are
Publikováno v:
Organometallics. 33:370-377
(NHC)2FeCl2 complexes undergo methoxide transfer in preference to aryl transfer from [(Aryl)B(OR)3]−, while addition of ArylBY2 (Y = Cl, OR) to (NHC)Fe–methoxide compounds leads only to formation of (NHC)BY2Aryl. The addition of PhBCl2 to (NHC)2F