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Autor:
Cristian Celis-Barros, Eduardo Solis-Céspedes, Dayán Páez-Hernández, Jillian Rankin, Thomas E. Albrecht-Schmitt, Yan Zhou, Alyssa N. Gaiser, David Dan, Ramiro Arratia-Pérez, Frankie D. White, Jasmine Colangelo
Publikováno v:
Inorganic Chemistry. 58:3457-3465
The reaction of SmI2 with dibenzo-30-crown-10 (DB30C10), followed by metathesis with [Bu4N][BPh4], allows for the isolation of [SmII(DB30C10)][BPh4]2 as bright-red crystals in good yield. Exposure of [Sm(DB30C10)]2+ to solvents containing trace water