Tuning the Properties of Metal-Organic Frameworks by Post-synthetic Modification

Autor: Sébastien Rochat, Harina Amer Hamzah, Laura K. Cadman, William J. Gee, Andrew D. Burrows, Jane V. Knichal

Publikováno v: Metal-Organic Frameworks

This chapter introduces the concept of post‐synthetic modification (PSM) in metal–organic framework (MOF) chemistry and provides examples of the use of this technique for a variety of applications. Following a brief introduction (Section 2.1), th

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https://doi.org/10.1002/9783527809097.ch2

Exploring structure-property relationships of silver 4-(Phenylethynyl)pyridine complexes

Autor: Paul R. Raithby, William J. Gee, Christopher A. Cameron, Andrew D. Burrows, Chick C. Wilson, Jonathan M. Skelton, Simon J. Teat, Jane V. Knichal, Kevin J. Gagnon

Publikováno v: Knichal, J V, Gee, W J, Cameron, C A, Skelton, J M, Gagnon, K J, Teat, S J, Wilson, C C, Raithby, P R & Burrows, A D 2017, ' Exploring structure-property relationships of silver 4-(Phenylethynyl)pyridine complexes ', European Journal of Inorganic Chemistry, vol. 2017, no. 13, pp. 1855-1867 . https://doi.org/10.1002/ejic.201601298
Knichal, J, Gee, W, Cameron, C, Skelton, J, Gagnon, K, Teat, S, Wilson, C, Raithby, P & Burrows, A 2017, ' Exploring structure-property relationships of silver 4-(phenylethynyl)pyridine complexes ', European Journal of Inorganic Chemistry, vol. 2017, no. 13, pp. 1855–1867 . https://doi.org/10.1002/ejic.201601298

Silver(salts demonstrate a strong preference for forming linear complexes when reacted with 4-(phenylethynyl)-pyridine (pep). The packing of these complexes was found to be strongly influenced by the counteranions, namely PF6-,BF4-, NO2-, NO3-, MeCO2

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https://www.research.manchester.ac.uk/portal/en/publications/exploring-structureproperty-relationships-of-silver-4phenylethynylpyridine-complexes(de9ed468-bb12-4024-9f6f-7b5b836e92ea).html

Inside Cover: An Iodine‐Vapor‐Induced Cyclization in a Crystalline Molecular Flask (Angew. Chem. Int. Ed. 20/2016)

Autor: Paul R. Raithby, Helena J. Shepherd, Chick C. Wilson, Jane V. Knichal, Andrew D. Burrows, William J. Gee

Publikováno v: Angewandte Chemie International Edition. 55:5872-5872

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https://doi.org/10.1002/anie.201603084

A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

Autor: Simon J. Teat, Mathew J. Bryant, Rafal Kulmaczewski, Helena J. Shepherd, Jane V. Knichal, Lauren E. Hatcher, George Tonge, Malcolm A. Halcrow, Kevin J. Gagnon, Paul R. Raithby

Publikováno v: Raithby, P, Hatcher, L, Bryant, M, Knichal, J, Shepherd, H, Tonge, G, Halcrow, M, Kulmacezewski, R, Gagnon, K & Teat, S 2016, ' A high pressure investigation of the order-disorder phase transition and accompanying spin crossover in [FeL1 2 ](ClO 4 ) 2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) ', Magnetochemistry, vol. 2, no. 1, pp. 9 . https://doi.org/10.3390/magnetochemistry2010009
Magnetochemistry; Volume 2; Issue 1; Pages: 9

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant an

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https://doi.org/10.3390/magnetochemistry2010009