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Publikováno v:
European Journal of Organic Chemistry. 2010:2971-2977
Studies of the reactions between group 4 metal chlorides (M = Ti, Zr, Hf) and methyllithium at –78 °C in toluene can lead to methylidene–metal complexes, H2C=MCl2, by a sequence of monomethylation, α-carbon lithiation and α,μ-elimination of L