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pro vyhledávání: '"Jana Lücken"'
Publikováno v:
European Journal of Inorganic Chemistry. 26
Autor:
Jana Lücken, Max C. Holthausen, Mohd Nazish, Brigitte Schwederski, Dietmar Stalke, Samir Kumar Sarkar, Wolfgang Kaim, Regine Herbst-Irmer, Christina M. Legendre, Martin Diefenbach, Herbert W. Roesky, Daniel J. Goffitzer
Publikováno v:
Inorganic chemistry. 60(14)
Herein, we report on a facile and selective one-pot synthetic route to silicon-boron radicals. Reduction of Br2BTip (Tip = 2,4,6-iPrC6H2) with KC8 in the presence of LSi-R affords LSi(tBu)-B(Br)Tip (1) and LSi(N(TMS)2)-B(Br)Tip (2) [L = PhC(NtBu)2].
Publikováno v:
Inorganic chemistry. 59(19)
Copper(I) hydride complexes represent a promising entry into formic acid dehydrogenation catalysis. Herein we present the spontaneous decarboxylation of a μ1,3-formate-bridged dicopper(II) complex ...