Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Jan O. V»gberg"'
Publikováno v:
Tetrahedron. 50:61-76
Fulvene-anions (vinyl cyclopentadienyl anions) are exclusively allylated in the exocyclic position by allylic chlorides, allylic acetates, and allylic carbonates in the presence of catalytic amounts of bis(dibenzylideneacetone)palladium(O) and triphe
Publikováno v:
Tetrahedron Letters. 32:5247-5250
6,6-Dimethylfulvene was regioselectively functionalized at the 7-position by reacting the fulvene anion 1 with allylic chlorides or allylic acetates in the presence of a palladium(0)-phosphine catalyst.
Autor:
Andreas Heumann, Sverker Hansson, Jan O. V»gberg, Björn Åkermark, Jan-Erling Bäckvall, Tobias Rein
Publikováno v:
Journal of Organometallic Chemistry. 369:433-444
In order to investigate the possibility of improving the selectivity in palladium-catalyzed acetoxylation of substituted cycloalkenes and linear alkenes, the influence of added strong acids has been studied. It was found that the product selectivity
Publikováno v:
Tetrahedron Letters. 30:137-140
Dienes 1 were transformed into γ-lactones via a novel stereocontrolled palladium-catalyzed lactonization reaction. The oxylactonization can be directed towards either a cis- or trans- addition across the diene.
Publikováno v:
Tetrahedron Letters. 25:2717-2720
Palladium-catalyzed oxidation of conjugated dienes in acetic acid containing CF 3 COOH/LiOOCCF 3 results in the formation of 1-acetoxy-4-trifluoroacetoxy-2-alkenes.