Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Jan Nicolaas Eddy Duchateau"'
Autor:
Guy Marin, Dagmar R. D'hooge, Ana Luisa Vaz, Paul Van Steenberge, Klaas Remerie, Julio C. Hernández-Ortiz, Carolina Toloza, Fons Schreurs, Jan Nicolaas Eddy Duchateau, Marie-Françoise Reyniers
Publikováno v:
AIChE Journal. 63:4944-4961
For post-polymerization modification, a novel kinetic Monte Carlo (kMC) modeling strategy for the description of the reaction event history and the evolution of the microstructure of individual macrospecies with a complex topology is presented. The k
Autor:
Jan Nicolaas Eddy Duchateau, Markus Busch, Peter Neuteboom, Carolina De Los Angeles Toloza Porras, Diego Mauricio Castañeda-Zúñiga, Sebastian Fries
Publikováno v:
Macromolecular Symposia. 360:78-86
Summary A combined experimental and computational approach is presented in order to study reactor fouling in high pressure LDPE tubular reactors. Indications are found that fouling is a process driven by low polymer diffusion speeds and higher fricti
Autor:
Guy Marin, Dagmar R. D'hooge, Marie-Françoise Reyniers, Carolina Toloza, Julio C. Hernández-Ortiz, Fons Schreurs, Paul Van Steenberge, Jan Nicolaas Eddy Duchateau
Publikováno v:
Chemical Engineering Journal. 377:119980
Free radical induced grafting (FRIG) of polyolefins is described at industrially relevant time scales at which phase segregation occurs, leading to the formation of a monomer- and polyolefin-rich phase. The mass transfer of oligomeric species is acco
Autor:
Fons Schreurs, Guy Marin, Jan Nicolaas Eddy Duchateau, Carolina Toloza, Julio C. Hernández-Ortiz, Marie-Françoise Reyniers, Paul Van Steenberge, Dagmar R. D'hooge
Publikováno v:
Macromolecular Theory and Simulations. 28:1900035
For industrial-scale continuous free radical induced grafting of polyethylene, which involves the contact of a monomer- and polymer-rich phase, it is demonstrated that the functionalization selectivity and grafting density can be significantly improv
Autor:
Marie-Françoise Reyniers, Guy Marin, Fons Schreurs, Carolina Toloza, Paul Van Steenberge, Jan Nicolaas Eddy Duchateau, Dagmar R. D'hooge, Julio C. Hernández-Ortiz
Publikováno v:
Macromolecular Theory and Simulations. 27:1800036
Radical‐induced grafting of polyethylene involves many reactions such as initiator dissociation, hydrogen abstraction, graft chain initiation, graft (de)propagation, crosslinking, and homo(de)polymerization. To ensure a successful grafting, both th