Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Jan M. Schümann"'
Autor:
Henrik F. König, Lars Rummel, Heike Hausmann, Jonathan Becker, Jan M. Schümann, Peter R. Schreiner
Publikováno v:
The Journal of Organic Chemistry. 87:4670-4679
We present an experimental and computational study of a cyclooctatetraene (COT)-based molecular balance disubstituted with commonly used silyl groups. Such groups often serve as protecting groups and are typically considered innocent bystanders. Our
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
We present a computational analysis of hexaphenylethane derivatives with heavier tetrels comprising the central bond. In stark contrast to parent hexaphenylethane, the heavier tetrel derivatives can readily be prepared. In order to determine the orig
Publikováno v:
Journal of the American Chemical Society. 143(1)
We present a comprehensive experimental study of a di-t-butyl-substituted cyclooctatetraene-based molecular balance to measure the effect of 16 different solvents on the equilibrium of folded versus unfolded isomers. In the folded 1,6-isomer, the two
Publikováno v:
The Journal of organic chemistry. 80(3)
We present an organocatalytic C-O-bond cross-coupling strategy to kinetically resolve racemic diols with aromatic and aliphatic alcohols, yielding enantioenriched esters. This one-pot protocol utilizes an oligopeptide multicatalyst, m-CPBA as the oxi