Cationic Heteroleptic Cyclometalated IridiumIII Complexes Containing Phenyl-Triazole and Triazole-Pyridine Clicked Ligands

Autor: Martin C. Feiters, Luisa De Cola, René M. Williams, Roeland J. M. Nolte, Jan M. M. Smits, Pablo Contreras-Carballada, Marco Felici

Publikováno v: Molecules, Vol 15, Iss 3, Pp 2039-2059 (2010)

Novel heteroleptic iridium complexes containing the 1-substituted-4-phenyl-1H-1,2,3-triazole (phtl) cyclometalating ligand have been synthesized. The 3+2 Huisgen dipolar cycloaddition method (‘click’ chemistry) was utilized to prepare a class of

Externí odkaz: https://doaj.org/article/a975236d4e3d4ac88c287666d0376d83

Carbenoid transfer reactions catalyzed by a ruthenium porphyrin macrocycle

Autor: Johannes A. A. W. Elemans, René de Gelder, Onno I. van den Boomen, Roeland J. M. Nolte, Alan E. Rowan, P. P. J. Schlebos, Ruud G. E. Coumans, Niels Akeroyd, Jan M. M. Smits, Theo P. J. Peters

Publikováno v: Tetrahedron, 73, 33, pp. 5029-5037
Tetrahedron
Tetrahedron, 73, 5029-5037

A ruthenium porphyrin functionalized with a cavity based on diphenylglycoluril is applied as a catalyst in carbenoid transfer reactions using α-diazoesters as substrates. The latter compounds contain a blocking group connected via an α,ω-dioxyalky

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a3291a9c2642df4c45a3b0af2eff6f3
https://hdl.handle.net/2066/177555

Formal Synthesis of Solanoeclepin A: Enantioselective Allene Diboration and Intramolecular 2+2 Photocycloaddition for the Construction of the Tricyclic Core

Autor: Henk Hiemstra, Ginger Lutteke, Brian J. J. Timmer, Jan H. van Maarseveen, Roel A. Kleinnijenhuis, René de Gelder, Jan M. M. Smits

Publikováno v: Chemistry : a European Journal, 22, 4, pp. 1266-1269
Chemistry-A European Journal, 22(4), 1266-1269. Wiley-VCH Verlag
Chemistry : a European Journal, 22, 1266-1269

An enantioselective synthesis of an intermediate in the Tanino total synthesis of solanoeclepin A has been developed. The key step was an intramolecular [2+2] photocycloaddition, which led to the tricyclo[5.2.1.0(1, 6)] decane core in six steps. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::47fc8279663aab9a915062c3c9703c82
https://hdl.handle.net/2066/156949

Mononuclear and dinuclear manganese compounds stabilized by supramolecular interactions

Autor: Ilpo Mutikainen, L. Jos de Jongh, Jan M. M. Smits, Marta Viciano-Chumillas, Urho Turpeinen, René de Gelder, Mónica Giménez-Marqués, Stefania Tanase, Jan Reedijk

Publikováno v: Journal of the Chemical Society. Dalton Transactions. Inorganic Chemistry, 41, 34, pp. 10249-10257
Journal of the Chemical Society. Dalton Transactions. Inorganic Chemistry, 41, 10249-10257
Dalton Transactions, 41(34), 10249-10257. Royal Society of Chemistry

New manganese compounds [Mn(HphpzMe)(2)(H(2)phpzMe)(HCO(2))] (1), [Mn(2)(phpzMe)(2)(HphpzMe)(2)(OCH(3))]·2CH(3)OH (2), Na{[Mn(HphpzPh)(phpzPh)(MeOH)(2)](2)}(HCO(2)) (3), [Mn(HphpzPh)(2)(EtOH)(2)]ClO(4)·2EtOH (4) and [Mn(HphpzPh)(2)N(3)] (5) were sy

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::54b7fe558fbb709afd5f664b4ccb8032
https://hdl.handle.net/11245/1.381055

Carbonyl Complexes of Rhodium with N-Donor Ligands: Factors Determining the Formation of Terminal versus Bridging Carbonyls

Autor: R. de Gelder, Wojciech I. Dzik, Theo P. J. Peters, C. Creusen, B. de Bruin, Jan M. M. Smits

Publikováno v: Organometallics
Organometallics, 29(7), 1629-1641. American Chemical Society
Organometallics, 29, 7, pp. 1629-1641
Organometallics, 29, 1629-1641

Cationic rhodium carbonyl complexes supported by a series of different N-3- and N-4-donor ligands were prepared, and their ability to form carbonyl-bridged species was evaluated. Complex [Rh(K3-bpa)(cod)r (1(+)) (bpa = bis(2-picolyBamine, cod = cis,c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::12821461fda3b925c4ce2dd2e42950d4
https://doi.org/10.1021/om901023n