Zobrazeno 1 - 10
of 23
pro vyhledávání: '"James E. Kickham"'
Publikováno v:
Organometallics. 23:3309-3318
The redox chemistry of phosphinimide-containing group IV metal complexes has been investigated. Reaction of the simple phosphinimide species CpTi(NPR3)Cl2 (R = Me 1, i-Pr 2) with Mg affords complexes formulated as [CpTiCl(μ-NPR3)]2 (R = Me 3, i-Pr 4
Autor:
Silke Courtenay, Todd Graham, Douglas W. Stephan, Pingrong Wei, Emily Hollink, Daryll G. Harrison, Wei Xu, Chad Beddie, James E. Kickham, Linda Koch, Aaron J. Hoskin, Jeffrey C. Stewart, Rupert Edward Von Haken Spence, Frédéric Guérin, Xiaoliang Gao
Publikováno v:
Organometallics. 22:1937-1947
A strategy for polymerization catalyst design has been developed based on the steric and electronic analogy of bulky phosphinimides to cyclopentadienyl ligands. To this end, the family of complexes of the form (Cp†)TiCl2(NPR3) has been prepared and
Publikováno v:
Organometallics. 21:1646-1653
A series of titanium−phosphinimide thiolate complexes were prepared employing either thiolate for chloride metathesis or protonolysis of metal−carbon bonds by thiols. In these ways the following species were obtained: CpTi(NPR‘3)(SR)2 (R‘ = i
Autor:
Douglas W. Stephan, James E. Kickham, and Edyta Urbanska, Frédéric Guérin, Jeffrey C. Stewart
Publikováno v:
Organometallics. 20:1175-1182
Multiple C−H bond activation occurs upon reaction of phosphinimide complexes of the form Cp‘(R3PN)TiMe2 (Cp‘ = Cp, indenyl; R = i-Pr, Cy, Ph) with excess AlMe3, affording the carbide complexes Cp‘Ti(μ2-Me)(μ2-NPR3)(μ4-C)(AlMe2)3 or in some
Publikováno v:
Angewandte Chemie. 112:3406-3409
Publikováno v:
Angewandte Chemie. 39:3263-3266
Publikováno v:
Polyhedron. 17:947-952
A limited review of the use of mixed-donor ligands that contain amides is presented. By combining amides with phosphines and amines in a chelating array, a variety of tridentate and macrocyclic ligands have been prepared. The synthesis and structures
Publikováno v:
Chemistry - A European Journal. 3:1203-1213
Publikováno v:
Inorganic Chemistry. 36:3480-3484
The new lithium amide LiN(SiMe2CH2NMe2)2 was prepared by reaction of NH3 with the corresponding silylamine Me2NSiMe2CH2NMe2 followed by addition of butyllithium. This lithium derivative exists as a dimer in the solid state wherein the two lithium ion
Autor:
Stephen J. Loeb, James E. Kickham
Publikováno v:
Organometallics. 14:3584-3587