Zobrazeno 1 - 10
of 38
pro vyhledávání: '"James E. Eilers"'
Autor:
George B. Richter-Addo, Anthony R. Ramuglia, Michael J. Shaw, Arghavan Fadamin, Erwin G. Abucayon, Jeremy R. Zink, James E. Eilers
Publikováno v:
ChemElectroChem. 5:861-871
The electrochemistry of several ruthenium porphyrin nitrosyl chloride complexes [Ru(por)(NO)Cl] have been examined in tetrahydrofuran. The complexes undergo 1-electron irreversible reductions which result in the diffusion-limited substitutions of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::92d0d85aa0f1c48caba9ff68ded83e4a
https://doi.org/10.1002/celc.201701001
https://doi.org/10.1002/celc.201701001
Autor:
James E. Eilers, Jonathan Lefton, Mortezaali Razzaghi, Mahdi Raghibi Boroujeni, Mortaza Derakhshani-Molayousefi, Binita Maharjan, Ormacinda R. White, Blake A. Hammann, Yun Lu
Publikováno v:
Journal of the American Chemical Society. 137:6653-6661
The observed 1° isotope effect on 2° KIEs in H-transfer reactions has recently been explained on the basis of a H-tunneling mechanism that uses the concept that the tunneling of a heavier isotope requires a shorter donor-acceptor distance (DAD) tha
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d29c26e43dc0cab8d8514862656158ed
https://doi.org/10.1021/jacs.5b03085
https://doi.org/10.1021/jacs.5b03085
Autor:
Daniel Roston, James E. Eilers, Sadra Kashefolgheta, Mortezaali Razzaghi, Yun Lu, Blake A. Hammann
Publikováno v:
The Journal of Organic Chemistry
We recently reported abnormal secondary deuterium kinetic isotope effects (2° KIEs) for hydride transfer reactions from alcohols to carbocations in acetonitrile (Chem. Comm. 2012, 48, 11337). Experimental 2° KIE values were found to be inflated on
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7b5006d0d7765dc1e3531c43aa3ac705
http://europepmc.org/articles/PMC3985929
http://europepmc.org/articles/PMC3985929
Publikováno v:
The Journal of Physical Chemistry A
We recently reported a study of the steric effect on the 1° isotope dependence of 2° KIEs for several hydride-transfer reactions in solution (J. Am. Chem. Soc. 2015, 137, 6653). The unusual 2° KIEs decrease as the 1° isotope changes from H to D,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::62e4305d710e36b9796d5abaaac724e6
https://hdl.handle.net/11858/00-001M-0000-002B-1CEE-C11858/00-001M-0000-002D-BDFA-111858/00-001M-0000-002A-D9DF-611858/00-001M-0000-002B-1CEF-A
https://hdl.handle.net/11858/00-001M-0000-002B-1CEE-C11858/00-001M-0000-002D-BDFA-111858/00-001M-0000-002A-D9DF-611858/00-001M-0000-002B-1CEF-A
Publikováno v:
The Journal of Organic Chemistry. 77:6825-6833
To assess the contribution of physical features to enzyme catalysis, the enzymatic reaction has to be compared to a relevant uncatalyzed reaction. While such comparisons have been conducted for some hydrolytic and radical reactions, it is most challe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6cd38920d7080b4cabec8ca5dbf15c33
https://doi.org/10.1021/jo300879r
https://doi.org/10.1021/jo300879r
Autor:
James E. Eilers, George B. Richter-Addo, Adam J Warhausen, Michael J. Shaw, Bradley L. Noble, Kenneth W Rodgers, Daniel L Cranford
Publikováno v:
Inorganic Chemistry. 49:9590-9598
A widely applicable fiber-optic UV-vis method to determine the spectra of in situ generated redox products and intermediates at or near an electrode surface is described mathematically and implemented experimentally. The quantitative spectral informa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::98afbb020caf84204950fb559f97c302
https://doi.org/10.1021/ic1012654
https://doi.org/10.1021/ic1012654
Autor:
Jeremy R. Zink, Erwin G. Abucayon, Anthony R. Ramuglia, Arghavan Fadamin, James E. Eilers, George B. Richter-Addo, Michael J. Shaw
Publikováno v:
ChemElectroChem. 5:820-820
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7016a9e342dc5fd191d2294d60d0de7d
https://doi.org/10.1002/celc.201800217
https://doi.org/10.1002/celc.201800217
Autor:
James E. Eilers, George B. Richter-Addo, Jeremy R. Zink, Anthony R. Ramuglia, Michael J. Shaw, Erwin G. Abucayon, Arghavan Fadamin
Publikováno v:
ChemElectroChem. 5:817-817
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::463a79b5055492b7c7b118cc4676c0fd
https://doi.org/10.1002/celc.201800218
https://doi.org/10.1002/celc.201800218
Publikováno v:
Organometallics. 28:5349-5357
The electrochemical and chemical reduction of CoCp(1,5-COD) (1, Cp = η5-C5H5; COD = cyclooctadiene) has been reinvestigated in THF. Whereas the initially formed monoanion 1− (E1/2 = −3.01 V vs Fc, ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::969ec17476090898dfdb741a99631b5f
https://doi.org/10.1021/om9003847
https://doi.org/10.1021/om9003847
Autor:
Deidre R. Eilers, Brian J. Duke, Brian O'Leary, James E. Eilers, Sungzong Kang, Arno Liberles
Publikováno v:
International Journal of Quantum Chemistry. 9:155-170
Molecular orbital electronic structure calculations for twelve polynuclear aromatic hydrocarbons were performed by the samo method. Results indicate that the carcinogenicity of such aromatic hydrocarbons is related to a K-region π-bond order greater
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9dc2d85df4325579188016ebb088e6b3
https://doi.org/10.1002/qua.560090714
https://doi.org/10.1002/qua.560090714