Zobrazeno 1 - 9 of 9 pro vyhledávání: '"Jameel A. Farooqi"'
1
An analysis of consecutive first-order reactions: protodeacetylation of diacetylmesitylene
Autor: Peter H. Gore, Jameel A. Farooqi
Publikováno v: Tetrahedron Letters. 18:2983-2986
In 89.8% sulphuric acid 1,3-diacetyl-2,4,6-trimethylbenzene undergoes two successive protodeacetylation stages and a final sulphonation to give 2,4,6-trimethylbenzenesulphonic acid. A kinetic analysis of the component reactions has been realised.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::00582cc6b78211a70836c0dd45290048
https://doi.org/10.1016/s0040-4039(01)83133-6
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2
Kinetic analysis of a single-path, and of a dual-path, sequence of four first-order reactions. The reactions of dibenzoylmesitylene and acetylbenzoylmesitylene in sulfuric acid
Autor: Gerald F. Moxon, David N. Waters, Jameel A. Farooqi, Peter H. Gore
Publikováno v: International Journal of Chemical Kinetics. 20:95-102
Dibenzoylmesitylene undergoes protiodeacylation in 89.8% (w/w) sulfuric acid at ca. 90°C, with subsequent sulfonation, to give mesitylenedisulfonic acid. The reaction involves a single-path sequence of four first-order reactions. The corresponding r
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8f423829e76c18c6ce30a16284a1cceb
https://doi.org/10.1002/kin.550200202
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5
ChemInform Abstract: Kinetic Analysis of a Single-Path, and of a Dual-Path, Sequence of Four First-Order Reactions. The Reactions of Dibenzoylmesitylene and Acetylbenzoylmesitylene in Sulfuric Acid
Autor: Jameel A. Farooqi, Gerald F. Moxon, Peter H. Gore, David N. Waters
Publikováno v: ChemInform. 19
Dibenzoylmesitylene undergoes protiodeacylation in 89.8% (w/w) sulfuric acid at ca. 90°C, with subsequent sulfonation, to give mesitylenedisulfonic acid. The reaction involves a single-path sequence of four first-order reactions. The corresponding r
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7e42eeddd7a4b26a3e8247c30457913d
https://doi.org/10.1002/chin.198821109
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6
Kinetic studies of Lewis acidity. Part 2. Catalysis by tin(IV) chloride, by some organotin(IV) chlorides, and by tin(II) chloride of the anionotropic rearrangement of 1-phenylprop-2-en-1-ol in tetramethylene sulphone solution
Autor: Ja'far Al-Ka'bi, Peter H. Gore, David N. Waters, Robert Hollingworth, Jameel A. Farooqi, Padraig C. Doolan
Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :501
The kinetics have been measured for the rearrangement of 1-phenylprop-2-en-1-ol (1) to 3-phenylprop-2-en-1-ol (2) in tetramethylene sulphone solution, catalysed by various tin(IV) chloride species. The rate coefficients, kn′ at 313.2 K, per unit co
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::85291cb57b94fb84c003f494f9cef8a2
https://doi.org/10.1039/p29860000501
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7
Kinetics of sulphodeacylation of dimesityl ketone: a dual-path sequence of first-order reactions
Autor: Jameel A. Farooqi, Peter H. Gore, David N. Waters, Gerald F. Moxon, Esmat F. Saad
Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :835
The kinetics of the conversion in 89.8%(w/w) sulphuric acid of 2,2′,4,4′,6,6′-hexamethylbenzophenone (A) into 2,4,6-trimethylbenzenesulphonic acid (D) were measured, and analysed in terms of the dual-path first-order reaction sequence (A)[graph
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::860735ca855f151fe76da7733171a9f3
https://doi.org/10.1039/p29800000835
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8
Protiodeacylation of 4-substituted 1-acetyl-2,6-dimethylbenzenes in sulphuric acid: kinetics and mechanism
Autor: David N. Waters, Ja'far Al-Ka'bi, Esmat F. Saad, Jameel A. Farooqi, Eric L. Short, Ahmed M. G. Nassar, Peter H. Gore
Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :943
In 89.8%(w/w) sulphuric acid rate coefficients (104k1/s–1) for the protiodeacetylation of 4-substituted (X) 1-acetyl-2,6-dimethylbenzenes (1) were, at 25 °C; X = Br, 0.468; I, 0.509; Cl, 0.635; H, 1.345; F, 2.52; Ph, 31.5; But, 38.6; and Me, 47.2.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::40fa159aed56172a5259d07ea04defe6
https://doi.org/10.1039/p29880000943
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9
Additivity of substituent effects in the alkaline hydrolysis of alkyl benzoates
Autor: Peter H. Gore, Abdur Rahim, Jameel A. Farooqi
Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :1921
The kinetics of hydrolysis of some methyl, ethyl, isopropyl, and t-butyl esters of substituted benzoic acids were studied in 70% v/v dioxan–water. The substituent effects and their additivity were examined. The hydrolysis of the methyl benzoates fo
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b5bd6c5772b8bfec25cb45acfeab1c83
https://doi.org/10.1039/p29760001921
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