Zobrazeno 1 - 10
of 21
pro vyhledávání: '"Jake D. Soper"'
Publikováno v:
Organometallics. 38:1868-1871
A 10-aza-9-phosphatriptycene is accessible on a gram scale, in three laboratory steps from commercially available precursors. Infrared spectroscopy of a rhodium(I) carbonyl complex bearing this lig...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::be466cb0637a3b7d848d270c108b1cd2
https://doi.org/10.1021/acs.organomet.9b00081
https://doi.org/10.1021/acs.organomet.9b00081
Publikováno v:
Angewandte Chemie International Edition. 57:1311-1315
Visible-light capture activates a thermodynamically inert CoIII -CF3 bond for direct C-H trifluoromethylation of arenes and heteroarenes. New trifluoromethylcobalt(III) complexes supported by a redox-active [OCO] pincer ligand were prepared. Coordina
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1db1959dad9ac9f55114f4213f613a83
https://doi.org/10.1002/anie.201711693
https://doi.org/10.1002/anie.201711693
Publikováno v:
Angewandte Chemie. 130:1325-1329
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ba5b846b6ecaa2b4f0448a82f70056cb
https://doi.org/10.1002/ange.201711693
https://doi.org/10.1002/ange.201711693
Autor:
Nicolaas P. van Leest, Quinton J. Bruch, Brooke N. Livesay, Jake D. Soper, John Bacsa, Kenneth I. Hardcastle, Bas de Bruin, Caleb F. Harris, Michael B. Bayless, Matthew P. Shores
Publikováno v:
Inorganic Chemistry, 56(20), 12421-12435. American Chemical Society
A new family of low-coordinate Co complexes supported by three redox-noninnocent tridentate [OCO] pincer-type bis(phenolate) N-heterocyclic carbene (NHC) ligands are described. Combined experimental and computational data suggest that the charge-neut
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cb03bc76125d953b22590139e3438e0d
https://doi.org/10.1021/acs.inorgchem.7b01906
https://doi.org/10.1021/acs.inorgchem.7b01906
Publikováno v:
European Journal of Inorganic Chemistry. 2012:554-561
The capacity of five-coordinate oxorhenium(V) anions with redox-active catecholate ligands to homolyze O2 and afford dioxorhenium(VII) products is utilized for the development of new aerobic alcohol oxidation catalysts. The reaction of [ReVII(O)2(cat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::54e7a23599246f5e3c726d8dfc4188dd
https://doi.org/10.1002/ejic.201101044
https://doi.org/10.1002/ejic.201101044
Publikováno v:
Inorganic Chemistry. 50:9864-9878
The addition of an [X](+) electrophile to the five-coordinate oxorhenium(V) anion [Re(V)(O)(ap(Ph))(2)](-) {[ap(Ph)](2-) = 2,4-di-tert-butyl-6-(phenylamido)phenolate} gives new products containing Re-X bonds. The Re-X bond-forming reaction is analogo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b55b651dc068b863f641191de70412b0
https://doi.org/10.1021/ic200923q
https://doi.org/10.1021/ic200923q
Publikováno v:
Journal of the American Chemical Society. 132:3879-3892
Five-coordinate oxorhenium(V) anions with redox-active catecholate and amidophenolate ligands are shown to effect clean bimetallic cleavage of O(2) to give dioxorhenium(VII) products. A structural homologue with redox-inert oxalate ligands does not r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e539ed726bff5e6855debedb9a4de3d2
https://doi.org/10.1021/ja910500a
https://doi.org/10.1021/ja910500a
Publikováno v:
Polyhedron. 29:164-169
Synthetic routes to new square planar cobalt complexes with redox-active amidophenolate chelates are presented. Contrary to previous reports, steric bulk on the ligands is not a prerequisite to formation of the low-coordinate materials. X-ray crystal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::38d394e8fcc2ebc8d87fcb0e5c497569
https://doi.org/10.1016/j.poly.2009.06.046
https://doi.org/10.1016/j.poly.2009.06.046
Autor:
Joel Rosenthal, Jillian L. Dempsey, Arthur J. Esswein, David R. Manke, Daniel G. Nocera, Jake D. Soper
Publikováno v:
Inorganic Chemistry. 44:6879-6892
Energy conversion cycles are aimed at driving unfavorable, small-molecule activation reactions with a photon harnessed directly by a transition-metal catalyst or indirectly by a transition-metal catalyst at the surface of a photovoltaic cell. The con
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44d5a55879d9744ec037baf563d434d9
https://doi.org/10.1021/ic0509276
https://doi.org/10.1021/ic0509276
Publikováno v:
Polyhedron. 23:323-329
The osmium(III) aniline complex TpOs(NH2Ph)Cl2 (OsIIINH2Ph) is formed on heating the triflate complex [Cp*2Fe][TpOsIII(OTf)Cl2] in the presence of aniline [Tp = hydrotris(1-pyrazolyl)borate]. It can also be prepared by reduction and protonation of th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a42ad1e5a27b6702376d0d4aaa1900e7
https://doi.org/10.1016/j.poly.2003.11.021
https://doi.org/10.1016/j.poly.2003.11.021